Enantioselective Raman spectroscopy (esR) for distinguishing between the enantiomers of 2-butanol

Literature Information

Publication Date 2018-05-16
DOI 10.1039/C8AN00705E
Impact Factor 4.616
Authors

Claudia C. Rullich


View Original

Abstract

The first experimental application of enantioselective Raman spectroscopy (esR) is demonstrated using the example of the chiral alcohol 2-butanol. Samples of the neat enantiomers and the racemic mixture were analyzed in a self-built Raman set-up. The Raman spectrum allows the discrimination of the chemical species. It is shown that the optical rotation of a Raman peak with a small depolarization ratio can be measured. In addition, without any sample modification, e.g. chiral solvent, the enantiomers are distinguishable at a suitable half-wave retarder angle detecting only the vertically polarized component of the Raman signal.

Related Literature

Effect of curing reaction types on the structures and properties of acetylene-containing thermosets: towards optimization of curing procedure

Junli Zhu, Liquan Wang, Jiaping Lin, Lei Du, Qixin Zhuang

2021-06-01 Paper

DOI: 10.1039/D0CP05580H

First principles characterisation of bio–nano interface

Ian Rouse, David Power, Erik G. Brandt, Matthew Schneemilch, Konstantinos Kotsis, Nick Quirke, Alexander P. Lyubartsev, Vladimir Lobaskin

2021-06-10 Paper

DOI: 10.1039/D1CP01116B

QM calculations predict the energetics and infrared spectra of transient glutamine isomers in LOV photoreceptors

Prokopis C. Andrikopoulos, Aditya S. Chaudhari, Yingliang Liu, Patrick E. Konold, John T. M. Kennis, Bohdan Schneider, Gustavo Fuertes

2021-06-18 Paper

DOI: 10.1039/D1CP00447F

Front cover

2021-06-23 Cover

DOI: 10.1039/D1CP90128A

Heparin remodels the microtubule-binding repeat R3 of Tau protein towards fibril-prone conformations

Xuewei Dong, Ruxi Qi, Qin Qiao, Xuhua Li, Fangying Li, Jiaqian Wan, Qingwen Zhang, Guanghong Wei

2021-08-20 Paper

DOI: 10.1039/D1CP02651H

Caveat when using ADC(2) for studying the photochemistry of carbonyl-containing molecules

Emanuele Marsili, Antonio Prlj, Basile F. E. Curchod

2021-06-04 Communication

DOI: 10.1039/D1CP02185K

Room-temperature diffusion of metal clusters on graphene

Mohammad Zarshenas, Victor Gervilla, Davide G. Sangiovanni, Kostas Sarakinos

2021-05-24 Paper

DOI: 10.1039/D1CP00522G

Fabrication of high quality electrochemical SERS (EC-SERS) substrates using physical vapour deposition

Carolyn G. Farling, Mary C. Stackaruk, Cory C. Pye, Christa L. Brosseau

2021-07-14 Paper

DOI: 10.1039/D1CP02416G

You might also like

Compound Q&A

What is the market or research trend for N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0)?

N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0) is increasingly being used ...

52818-63-0N-(4-Methoxybenzyl)-...
Compound Q&A

What precautions should be taken when handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate (CAS: 1050507-06-6)?

When handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate, appropriate p...

1050507-06-6Ethyl 4-(2-chlorophe...
Compound Q&A

What regulatory guidelines apply to diethyldiselane (CAS: 628-39-7)?

Diethyldiselane (CAS: 628-39-7) is classified under the Globally Harmonized Syst...

628-39-7Diethyldiselane
Compound Q&A

What is the market or research trend for oxocopper (CAS: 12053-18-8)?

The market for oxocopper (CAS: 12053-18-8) is primarily driven by its use in cat...

12053-18-8oxocopper; oxo-(oxoc...
Compound Q&A

What is the market or research trend for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-carboxylic acid?

The market for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-c...

1268519-54-55-{[(2-Methyl-2-prop...
Compound Q&A

What is 2-(1-Pyrrolidinyl)-4-pyridinamine (CAS: 35981-63-6)?

2-(1-Pyrrolidinyl)-4-pyridinamine is a chemical compound with the CAS number 359...

35981-63-62-(1-Pyrrolidinyl)-4...
Compound Q&A

What are the physical and chemical properties of 2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1)?

2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1) is a crystalline sol...

91556-75-12-(3-Pyridinyl)-1-az...
Compound Q&A

How is (S)-Alpha-allyl-proline hydrochloride (CAS: 129704-91-2) typically synthesized?

(S)-Alpha-allyl-proline hydrochloride is usually synthesized via a Wittig reacti...

129704-91-2(S)-Alpha-allyl-prol...
Compound Q&A

What is 3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5)?

3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5) is an organic compound w...

4857-42-53-Methyl-1,2-oxazole...
Compound Q&A

How is Lys-SMCC-DM1 (CAS: 1281816-04-3) typically synthesized?

Lys-SMCC-DM1 is synthesized via a multi-step process involving the coupling of S...

1281816-04-3Lys-SMCC-DM1

Source Journal

Analyst

Analyst
CiteScore: 7.8
Self-citation Rate: 5.6%
Articles per Year: 653

Analyst publishes analytical and bioanalytical research that reports premier fundamental discoveries and inventions, and the applications of those discoveries, unconfined by traditional discipline barriers.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.