Determination of the propagation rate coefficient of acrylonitrile

Literature Information

Publication Date 2010-03-04
DOI 10.1039/C0PY00019A
Impact Factor 5.582
Authors

Tanja Junkers, Sandy P. S. Koo, Christopher Barner-Kowollik


View Original

Abstract

For the first time, the propagation rate coefficient kp of acrylonitrile has been determined in a broad temperature range in propylene carbonate solution via the pulsed laser polymerization–size exclusion chromatography technique employing a high frequency pulsed laser system. kp was determined to fit the Arrhenius relation ln(kp/L mol−1 s−1) = 14.42 − 1855K/T.

Related Literature

A stereodivergent, two-directional synthesis of stereoisomeric C-linked disaccharide mimetics

Michael Harding, Robert Hodgson, Tahir Majid, Kenneth J. McDowall

2002-12-17 Paper

DOI: 10.1039/B208781B

Hydride-exchange reactions between NADH and NAD+ model compounds under non-steady-state conditions. Apparent and real kinetic isotope effects

Yun Lu, Yixing Zhao, Kishan L. Handoo, Vernon D. Parker

2002-11-22 Paper

DOI: 10.1039/B208186E

Diastereoselective construction of structurally diverse 2,3-dihydroquinolin-4-one scaffolds via redox neutral cascade [1,7]-hydride transfer/cyclization

Ronghao Xie, Shixiao Chen, Xianping Xiang, Xiangcong Yin, Lubin Xu, Shuai-Shuai Li, Liang Wang, Fengying Dong

2021-12-07 Research Article

DOI: 10.1039/D1QO01530C

Refined methods for the synthesis of meso-substituted A3- and trans-A2B-corroles

Daniel T. Gryko, Beata Koszarna

2002-12-09 Paper

DOI: 10.1039/B208950E

l-Dopa and dopamine conjugated naphthalenediimides modulate amyloid β toxicity

Madhu Ramesh, Pandeeswar Makam, Chandrashekhar Voshavar, Harshavardhan Khare, Kolla Rajasekhar, Suryanarayanarao Ramakumar, Thimmaiah Govindaraju

2018-09-28 Paper

DOI: 10.1039/C8OB01691G

Copper-catalyzed oxidative multicomponent reaction: synthesis of imidazo fused heterocycles with molecular oxygen

Xianwei Li, Tianzhang Wang, Yu-Jing Lu, Shaomin Ji, Yanping Huo, Bifu Liu

2018-08-02 Paper

DOI: 10.1039/C8OB01532E

Purine-substituted imidazolium mesomeric betaines and their tautomeric N-heterocyclic carbenes. Formation of a cyclic borane adduct

Jiaxi Zhang, Eike G. Hübner, Jan C. Namyslo, Martin Nieger, Andreas Schmidt

2018-09-05 Paper

DOI: 10.1039/C8OB01916A

Metal- and base-free synthesis of functionalized α,α-difluoroimines via electrophilic fluorination of N-substituted enamines

Fangyi Li, Changfu Qiu, Guangwei Yin, Chunhua Wang, Zheng Li

2018-09-13 Communication

DOI: 10.1039/C8OB01941J

Synthesis of difluoromethylated enynes by the reaction of α-(trifluoromethyl)styrenes with terminal alkynes

Mingsheng Wu, Xianghu Zhao, Yisen Liu, Song Cao

2018-09-11 Paper

DOI: 10.1039/C8OB02117A

Functionalization of diazotetronic acid and application in a stereoselective modular synthesis of pulvinone, aspulvinones A–E, G, Q and their analogues

Amarender Manchoju, Ritesh A. Annadate, Lise Desquien, Sunil V. Pansare

2018-08-10 Paper

DOI: 10.1039/C8OB01511B

You might also like

Compound Q&A

What is the market or research trend for N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0)?

N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0) is increasingly being used ...

52818-63-0N-(4-Methoxybenzyl)-...
Compound Q&A

What precautions should be taken when handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate (CAS: 1050507-06-6)?

When handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate, appropriate p...

1050507-06-6Ethyl 4-(2-chlorophe...
Compound Q&A

What regulatory guidelines apply to diethyldiselane (CAS: 628-39-7)?

Diethyldiselane (CAS: 628-39-7) is classified under the Globally Harmonized Syst...

628-39-7Diethyldiselane
Compound Q&A

What is the market or research trend for oxocopper (CAS: 12053-18-8)?

The market for oxocopper (CAS: 12053-18-8) is primarily driven by its use in cat...

12053-18-8oxocopper; oxo-(oxoc...
Compound Q&A

What is the market or research trend for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-carboxylic acid?

The market for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-c...

1268519-54-55-{[(2-Methyl-2-prop...
Compound Q&A

What is 2-(1-Pyrrolidinyl)-4-pyridinamine (CAS: 35981-63-6)?

2-(1-Pyrrolidinyl)-4-pyridinamine is a chemical compound with the CAS number 359...

35981-63-62-(1-Pyrrolidinyl)-4...
Compound Q&A

What are the physical and chemical properties of 2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1)?

2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1) is a crystalline sol...

91556-75-12-(3-Pyridinyl)-1-az...
Compound Q&A

How is (S)-Alpha-allyl-proline hydrochloride (CAS: 129704-91-2) typically synthesized?

(S)-Alpha-allyl-proline hydrochloride is usually synthesized via a Wittig reacti...

129704-91-2(S)-Alpha-allyl-prol...
Compound Q&A

What is 3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5)?

3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5) is an organic compound w...

4857-42-53-Methyl-1,2-oxazole...
Compound Q&A

How is Lys-SMCC-DM1 (CAS: 1281816-04-3) typically synthesized?

Lys-SMCC-DM1 is synthesized via a multi-step process involving the coupling of S...

1281816-04-3Lys-SMCC-DM1

Source Journal

Polymer Chemistry

Polymer Chemistry
CiteScore: 8.6
Self-citation Rate: 7.3%
Articles per Year: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.