(S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine

Basic Information

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CAS Number

277306-29-3

Molecular Formula

C32H40FeP2

Molecular Weight

552.55 g/mol

Basic Physical Properties

Melting Point

No data available

Boiling Point

No data available

Density

No data available

Flash Point

No data available

Vapor Pressure

No data available

Specific Rotation

+412° ±15° (c 0.5, CHCl3)

SMILES

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[Fe].C1CCCC1.C[C@H](P(C(C)(C)C)C(C)(C)C)C1CCCC1P(C1=CC=CC=C1)C1=CC=CC=C1

InChI

InChI=1S/C27H40P2.C5H10.Fe/c1-21(29(26(2,3)4)27(5,6)7)24-19-14-20-25(24)28(22-15-10-8-11-16-22)23-17-12-9-13-18-23;1-2-4-5-3-1;/h8-13,15-18,21,24-25H,14,19-20H2,1-7H3;1-5H2;/t21-,24?,25?;;/m0../s1

InChIKey

KEERMMZARKKVBY-IPMISBIPSA-N

LogP

9.7034

Topological Polar Surface Area

0.0 Å²

Hydrogen Bond Donor/Acceptor

0 / 0

Complexity

467

Safety Information

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Hazard Statement

Synonyms & References

English

1,2,3,4,5-Cyclopentanepentayl, compd. with 1-[(1S)-1-[bis(1,1-dim ethylethyl)phosphino]ethyl]-2-(diphenylphosphino)-1,2,3,4,5-cyclo pentanepentayl, iron salt (1:1:1)
(2S)-1-[(1S)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene
(S)-1-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]-ETHYLDI-TERT.-BUTYLPHOSPHINE
(S)-(+)-1-[(R)-2-(Diphenylphosphino)ferrocenyl]ethyldi-t-butylphosphine,min.97%
(s,s)-1-[1-(di-tert-butylphosphino)ethyl]-2-(diphenylphosphino]ferrocene (acc to cas)
(S)-(+)-1-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE, MIN. 97%
(S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
Josiphos SL-J002-2, (2S)-1-[(1S)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene (acc to CAS)
Ferrocene,1-[(1S)-1-[bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)-, (2S)-(9CI)
(S)-1-[(R{p})-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
(S)-(+)-1-[(R)-2-(Diphenylphosphino)ferrocenyl]ethyldi-t-butylphosphine
(S)-1-[(RP)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
((R)-2-AMINO-1-PHENYL-ETHYL)-CARBAMIC ACID TERT-BUTYL ESTER
(R)-(-)-1-[(butoxycarbonyl)amino]-1-phenyleth-2-ylamine
(R)-(-)-1-[(S)-2-(diphenylphosphino)ferrocenyl]eth
(R)-TERT-BUTYL 2-AMINO-1-PHENYLETHYLCARBAMATE
(S)-(+)-1-[(R)-2-(diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine
(S,R)-t-Bu-Josiphos
[(1R)-2-AMINO-1-PHENYLETHYL]-CARBAMIC ACID 1,1-DIMETHYLETHYL ESTER
1-diphenylphosphino-2-di-tert-butylphosphinoethylferrocene
Josiphos SL-J002-2

MDL Number

MFCD01074443

Customs Code

29319090

FAQ

What are the physical and chemical properties of (S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine (CAS: 277306-29-3)?

The compound has a crystalline form and a molecular weight of approximately 601.4 g/mol. It is poorly soluble in water but soluble in organic solvents like chloroform and THF. Chemically, it is known for its stability in air and its reactivity in coordination chemistry, particularly in catalytic systems.

How is (S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine (CAS: 277306-29-3) typically synthesized?

This compound is synthesized through a multi-step process involving the reaction of di-tert-butylphosphine with the corresponding 2-(diphenylphosphino)ferrocene derivative. The synthesis involves careful control of reaction conditions to achieve high yield and selectivity.

What industries use (S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine (CAS: 277306-29-3)?

This compound is primarily used in the pharmaceutical industry for catalytic processes in drug synthesis. It is also utilized in the polymer industry for the controlled polymerization of monomers and in the semiconductor industry for catalytic applications.

What precautions should be taken when handling (S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine (CAS: 277306-29-3)?

Proper handling requires the use of personal protective equipment (PPE) such as gloves and safety glasses. Work should be conducted in a fume hood to minimize exposure. Spills should be cleaned up using appropriate absorbents, and the material safety data sheet (MSDS) should be consulted for detailed handling instructions.