N-Methyl-3-(1-naphthyloxy)-3-(2-thienyl)-1-propanamine hydrochloride (1:1)
CAS Number:
1188266-11-6
Molecular Formula:
C18H20ClNOS
Reply to the ‘Comment on “Lewis acid-surfactant complex catalyzed polymerization in aqueous dispersed media: cationic or radical polymerization?”’ by I. V. Vasilenko, F. Ganachaud and S. V. Kostjuk, Polym. Chem., 2024, 15, DOI: 10.1039/D3PY00661A
Literature Information
Publication Date
2024-01-03
DOI
10.1039/D3PY01067H
Impact Factor
5.582
Authors
Aurelie Destephen
View Original
Abstract
In our previous work we concluded that the Lewis acid-surfactant complex catalyzed polymerization of styrene and other monomers in aqueous dispersed media does not proceed by a cationic polymerization. In a subsequent reply, Vasilenko et al. have suggested that this conclusion is incorrect. Here, we respond to the points raised by Vasilenko et al. and reassert our position that the experimental evidence is more consistent with a radical polymerization than a cationic polymerization and that achieving high molecular weight polymers by a cationic polymerization is not possible in aqueous systems at elevated temperatures unless chain transfer reactions are suppressed.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
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Molecular Formula:
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Molecular Formula:
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