Living polymerization of arylisocyanide initiated by the phenylethynyl palladium(ii) complex

Literature Information

Publication Date 2014-08-11
DOI 10.1039/C4PY01023J
Impact Factor 5.582
Authors

Ya-Xin Xue, Jia-Li Chen, Zhi-Qiang Jiang, Zhipeng Yu, Na Liu, Jun Yin, Yuan-Yuan Zhu, Zong-Quan Wu


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Abstract

A family of air-stable phenylethynyl palladium complexes was unexpectedly found to initiate the polymerization of phenyl isocyanide in a living/controlled chain growth manner, affording well-defined, stereoregular poly(phenyl isocyanide)s in high yield with controlled molecular weights and narrow molecular weight distributions.

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Polymer Chemistry

Polymer Chemistry
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