Living polymerization of arylisocyanide initiated by the phenylethynyl palladium(ii) complex
Literature Information
Ya-Xin Xue, Jia-Li Chen, Zhi-Qiang Jiang, Zhipeng Yu, Na Liu, Jun Yin, Yuan-Yuan Zhu, Zong-Quan Wu
A family of air-stable phenylethynyl palladium complexes was unexpectedly found to initiate the polymerization of phenyl isocyanide in a living/controlled chain growth manner, affording well-defined, stereoregular poly(phenyl isocyanide)s in high yield with controlled molecular weights and narrow molecular weight distributions.
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