RAFT polymerization and thermal behavior of trimethylphosphonium polystyrenes for anion exchange membranes

Literature Information

Publication Date 2010-11-15
DOI 10.1039/C0PY00293C
Impact Factor 5.582
Authors

Kristoffer K. Stokes, Joshua A. Orlicki, Frederick L. Beyer


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Abstract

Ionomers of trimethyl(4-vinylbenzyl)phosphonium chloride and styrene comonomers were synthesized with between 15 and 98 mol% ionic content. The thermal properties were explored and a significant increase in the glass transition of the high ion content polymers was found, most likely due to ion aggregation into clusters.

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Polymer Chemistry

Polymer Chemistry
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