Branching out with aminals: microporous organic polymers from difunctional monomers
Literature Information
Andrea Laybourn, Robert Dawson, Rob Clowes, Jonathan A. Iggo, Andrew I. Cooper, Yaroslav Z. Khimyak, Dave J. Adams
Microporous organic polymers (MOPs) have been prepared via one-pot polycondensation reactions between aldehydes and amines. Primary amines were reacted with imines to produce porous polymers from A2 + B2 monomer combinations. The resulting networks exhibit BET surface areas in the range 500ā600 m2 gā1. This approach opens up the possibility of synthesising MOPs using readily-available and inexpensive precursors.
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