Main-chain second-order nonlinear optical polyaryleneethynylenes containing isolation chromophores: enhanced nonlinear optical properties, improved optical transparency and stability
Literature Information
Publication Date
2013-03-26
DOI
10.1039/C3PY00257H
Impact Factor
5.582
Authors
Wenbo Wu, Shaohui Xin, Zhen Xu, Cheng Ye, Jingui Qin, Zhen Li
View Original
Abstract
In this paper, five nitro azo chromophore based main-chain second-order nonlinear optical (NLO) polyaryleneethynylenes are successfully prepared, in which isolation chromophore moieties (sulfonyl ones) with different concentrations were introduced to improve the poling efficiency of the resultant polymers. Thanks to the effect of the isolation chromophore, P5 exhibited the largest d33 value of 111.1 pm V−1 as well as the best thermal stability and optical transparency, indicating that the isolation chromophore moieties could alleviate the “nonlinearity-stability trade off” and “nonlinearity-transparency trade off” in the NLO area efficiently.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
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Recommended Compounds
![2-Methyl-2-propanyl [(2S)-1-hydroxy-3-(4-hydroxyphenyl)-2-propanyl]carbamate structure](https://static.chemtradehub.com/structs/833/83345-46-4-eec2.webp "2-Methyl-2-propanyl [(2S)-1-hydroxy-3-(4-hydroxyphenyl)-2-propanyl]carbamate structure")
2-Methyl-2-propanyl [(2S)-1-hydroxy-3-(4-hydroxyphenyl)-2-propanyl]carbamate
CAS Number:
83345-46-4
Molecular Formula:
C14H21NO4
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