An improved chemical model for the quantitative description of the front propagation in the tetrathionate–chlorite reaction

Literature Information

Publication Date 2010-01-15
DOI 10.1039/B920618C
Impact Factor 3.676
Authors

Gábor Peintler, György Csekő, Andrea Petz, Attila K. Horváth


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Abstract

It is experimentally proven that the stoichiometry of the tetrathionate–chlorite reaction is 2S4O2−6 + 8½ClO−2 + 6H2O = 8SO2−4 + ClO−3 + 7½Cl− + 12H+ near 1 : 4 molar ratio of the reactants. Re-evaluation of the previously measured front velocity—concentration curves also shows that this stoichiometry along with both the rate equation r = (1.6 × 105 M−3 s−1 [H+]2 + 3.6 × 107 M−4 s−1 [H+]3)[S4O2−6][ClO−2]and the protonation processes existing in the present system allow us to describe the front velocity as a function of the initial concentration of the reactants quantitatively. Some consequences detailed in the conclusions may concern not only uniquely the tetrathionate–chlorite reaction but any front propagation study including H+ as an autocatalyst.

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DOI: 10.1039/C8CP91834A

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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