X3 synthon geometries in two-dimensional halogen-bonded 1,3,5-tris(3,5-dibromophenyl)benzene self-assembled nanoarchitectures on Au(111)-( )
Literature Information
David Peyrot, Mathieu G. Silly, Fabien Silly
The self-assembly of star-shaped 1,3,5-tris(3,5-dibromophenyl)benzene molecules on Au(111)-() in a vacuum is investigated using scanning tunneling microscopy and core-level spectroscopy. Scanning tunneling microscopy shows that the molecules self-assemble into a hexagonal porous halogen-bonded nanoarchitecture. This structure is stabilized by X3-A synthons composed of three type-II halogen-interactions (halogen-bonds). The molecules are oriented along the same direction in this arrangement. Domain boundaries are observed in the hcp region of the herringbone gold surface reconstruction. Molecules of the neighboring domains are rotated by 180°. The domain boundaries are stabilized by the formation of X3-B synthons composed of two type-II and one type-I halogen-interactions between molecules of the neighboring domains. Core-level spectroscopy confirms the existence of two types of halogen-interactions in the organic layer. These observations show that the gold surface reconstructions can be exploited to modify the long-range supramolecular halogen-bonded self-assemblies.
Related Literature
Correction: Surface heterogeneity and inhomogeneous broadening of vibrational line profiles
Skandar Taj, Diane Baird, Alexander Rosu-Finsen, Martin R. S. McCoustra
DOI: 10.1039/C9CP90226K
A quantum chemical study of hydrogen adsorption on carbon-supported palladium clusters
Lisa Warczinski, Christof Hättig
DOI: 10.1039/C9CP04606B
Zn-Doped Cu(100) facet with efficient catalytic ability for the CO2 electroreduction to ethylene
Yuefeng Zhang, Yong Zhao, Caiyun Wang, Zengxi Wei, Junliang Yang
DOI: 10.1039/C9CP03692J
A DNP-hyperpolarized solid-state water NMR MASER: observation and qualitative analysis
Emmanuelle M. M. Weber, Dennis Kurzbach, Daniel Abergel
DOI: 10.1039/C9CP03334C
Graphyne-anchored single Fe atoms as efficient CO oxidation catalysts as predicted by DFT calculations
Si Wu, Yuan Yuan, Hui Mao, Baotao Kang
DOI: 10.1039/D0CP00178C
Highly fluorescent hybrid Au/Ag nanoclusters stabilized with poly(ethylene glycol)- and zwitterion-modified thiolate ligands
Dinesh Mishra, Sisi Wang, Zhicheng Jin, Yan Xin, Eric Lochner, Hedi Mattoussi
DOI: 10.1039/C9CP03723C
Phase transition and electronic properties of skutterudite-type IrP3 under high pressure
Xuejiao Ma, Dan Zhou, Yan Yan, Jing Xu, Siyuan Liu, Yulan Wang, Manai Cui, Yuheng Cheng, Yu Miao, Yanhui Liu
DOI: 10.1039/C9CP02422K
Contrasting the hydration thermodynamics of methane and methanol
DOI: 10.1039/C9CP03213D
Correction: Thermo-orientation in fluids of arbitrarily shaped particles
Andrea Gardin, Alberta Ferrarini
DOI: 10.1039/D0CP90053B
Correction: A hexagonal Ni6 cluster protected by 2-phenylethanethiol for catalytic conversion of toluene to benzaldehyde
Anthony M. S. Pembere, Chaonan Cui, Rajini Anumula, Haiming Wu, Pan An, Tongling Liang, Zhixun Luo
DOI: 10.1039/D0CP90052D
You might also like
Is 6-(3-Fluorophenyl)picolinic acid (CAS: 887982-40-3) safe?
6-(3-Fluorophenyl)picolinic acid is generally considered safe for laboratory use...
What industries use (3R)-3-Pyrrolidinol (CAS: 2799-21-5)?
(3R)-3-Pyrrolidinol is used in the pharmaceutical industry as a precursor for dr...
What precautions should be taken when handling (4R,5R)-4,5-Diethoxycarbonyl-2,2-dimethyldioxolane (CAS: 59779-75-8)?
When handling (4R,5R)-4,5-Diethoxycarbonyl-2,2-dimethyldioxolane (CAS: 59779-75-...
How is 1-(6-Chloroimidazo[1,2-b]pyridazin-3-yl)ethanone (CAS: 90734-71-7) typically synthesized?
1-(6-Chloroimidazo[1,2-b]pyridazin-3-yl)ethanone is often synthesized via a mult...
What is the market or research trend for N-Ethyl-3,4-dimethylbenzylamine (CAS: 39180-83-1)?
The market for N-Ethyl-3,4-dimethylbenzylamine (CAS: 39180-83-1) remains steady,...
What is Tert-butyl 3-(pyrrolidin-1-yl)azetidine-1-carboxylate (CAS: 1019008-21-9)?
Tert-butyl 3-(pyrrolidin-1-yl)azetidine-1-carboxylate is a chemical compound wit...
What regulatory guidelines apply to 1-Bromo-3-chloro-2,4-dimethoxybenzene (CAS: 1228956-93-1)?
1-Bromo-3-chloro-2,4-dimethoxybenzene (CAS: 1228956-93-1) falls under the classi...
Is 8-Bromo-2-methyl-3,4-dihydroisoquinolin-1(2H)-one (CAS: 1368622-07-4) safe?
The safety of 8-Bromo-2-methyl-3,4-dihydroisoquinolin-1(2H)-one (CAS: 1368622-07...
Is Benzyl [(3S)-2,6-dioxo-3-piperidinyl]carbamate (CAS: 22785-43-9) safe?
Benzyl [(3S)-2,6-dioxo-3-piperidinyl]carbamate is generally safe when handled wi...
How should 1-{[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]sulfonyl}pyrrolidine (CAS: 928657-21-0) be stored?
1-{[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]sulfonyl}pyrrolidine s...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.













![[4-Chloro-3-(diethylcarbamoyl)phenyl]boronic acid structure [4-Chloro-3-(diethylcarbamoyl)phenyl]boronic acid structure](https://static.chemtradehub.com/structs/871/871332-68-2-0e3b.webp)
![Benzyl spiro[indole-3,4'-piperidine]-1(2H)-carboxylate hydrochloride (1:1) structure Benzyl spiro[indole-3,4'-piperidine]-1(2H)-carboxylate hydrochloride (1:1) structure](https://static.chemtradehub.com/structs/159/159635-46-8-8de0.webp)