Copper catalyzed atom transfer radical cascade reactions in the presence of free-radical diazo initiators as reducing agents
Literature Information
Carolynne Ricardo, Tomislav Pintauer
Exceptional activity of [CuII(TPMA)Cl][Cl] (TPMA = tris(2-pyridylmethyl)amine) complex in atom transfer radical addition (ATRA) of CCl4 to 1,6-dienes followed by sequential atom transfer radical cyclization (ATRC) in the presence of free-radical diazo initiators as reducing agents is reported.
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