Copper catalyzed atom transfer radical cascade reactions in the presence of free-radical diazo initiators as reducing agents

Literature Information

Publication Date 2009-05-05
DOI 10.1039/B905839G
Impact Factor 6.222
Authors

Carolynne Ricardo, Tomislav Pintauer


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Abstract

Exceptional activity of [CuII(TPMA)Cl][Cl] (TPMA = tris(2-pyridylmethyl)amine) complex in atom transfer radical addition (ATRA) of CCl4 to 1,6-dienes followed by sequential atom transfer radical cyclization (ATRC) in the presence of free-radical diazo initiators as reducing agents is reported.

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