Tetrameric molecular bowl assembled from glycoluril building blocks

Literature Information

Publication Date 2008-04-04
DOI 10.1039/B800785C
Impact Factor 6.222
Authors

Neng-Fang She, Xiang-Gao Meng, Meng Gao, An-Xin Wu, Lyle Isaacs


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Abstract

Glycoluril derivative 1—whose bulky Ph–CC– substituents prevent formation of H-bonded tapes—undergoes solvent dependent assembly in the crystal; a tetrameric molecular bowl is formed by R44(24) H-bonding interactions from CH2Cl2 whereas DMF results in H-bond dimerization followed by oligomerization via C–H⋯π interactions.

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