Zwitterionic π-radical involving EDT-TTF-imidazole and F4TCNQ: redox properties and self-assembled structure by hydrogen-bonds and multiple S⋯S interactions

Literature Information

Publication Date 2007-07-25
DOI 10.1039/B707113B
Impact Factor 6.222
Authors

Tsuyoshi Murata, Yumi Yakiyama, Yoshie Nishimura, Tomoaki Ise, Daisuke Shiomi, Kazunobu Sato, Takeji Takui


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Abstract

The reaction between an imidazole-functionalized EDT-TTF and F4TCNQ produced a zwitterionic π-radical, which formed a self-assembled structure by the cooperation of hydrogen-bonds and multiple S⋯S interactions and exhibited three-step oxidation processes and a high electrical conductivity as a single-component organic molecule.

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Chemical Communications

Chemical Communications
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