Significant and differential acceleration of dephosphorylation of the insecticides, paraoxon and parathion, caused by alkali metal ethoxides

Literature Information

Publication Date 2003-11-07
DOI 10.1039/B310055C
Impact Factor 6.222
Authors

Ik-Hwan Um, Sang-Eun Jeon, Mi-Hwa Baek, Hye-Ran Park


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Abstract

In the reaction of paraoxon with alkali metal ethoxides, ion-paired EtO−M+ species are more reactive than the dissociated EtO− with the reactivity order EtO−Li+ > EtO−Na+ > EtO−K+ > EtO−, while in the reaction of parathion, the reactivity follows the order EtO−K+ > EtO− > EtO−Na+ > EtO−Li+.

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