Modelling catalytic turnover frequencies in ionic liquids: the determination of the bimolecular rate constant for solvent displacement from [(C6H6)Cr(CO)2Solv] in 1-n-butyl-3-methylimidazolium hexafluorophosphate

Literature Information

Publication Date 2004-02-03
DOI 10.1039/B315781D
Impact Factor 6.222
Authors

Konrad Swiderski, Andrew McLean, Charles M. Gordon, D. H. Vaughan


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Abstract

The bimolecular rate constant for solvent displacement, k2, from [(C6H6)Cr(CO)2Solv] by an incoming ligand has been determined in the room temperature ionic liquid, [bmim][PF6], and is compared to that for the same process in cyclohexane and dichloroethane.

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