Mixed halo/hydroxy carborane anions: thermally stable platforms for hydronium ion isolation
Literature Information
Publication Date
2004-02-16
DOI
10.1039/B314475E
Impact Factor
6.222
Authors
Daniel J. Stasko, Kevin J. Perzynski, Mark A. Wasil
View Original
Abstract
Hydroxylation of the robust, weakly coordinating hexahalo- carborane anion system, CB11H6Br6−1, produces a new class of anion with mixed halo/hydroxyl substituents, HCB11(OH)5Br6−1 which can be used to isolate a number of hydronium cation salts including an ‘ice tautomer’ composed of hydronium cation, anion hydroxyl groups and coordinated water molecules.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry
Recommended Compounds
![4-Penten-1-yl 2-[(2-furylmethyl)(1H-imidazol-1-ylcarbonyl)amino]butanoate structure](https://static.chemtradehub.com/structs/101/101903-30-4-ac34.webp "4-Penten-1-yl 2-[(2-furylmethyl)(1H-imidazol-1-ylcarbonyl)amino]butanoate structure")
4-Penten-1-yl 2-[(2-furylmethyl)(1H-imidazol-1-ylcarbonyl)amino]butanoate
CAS Number:
101903-30-4
Molecular Formula:
C18H23N3O4
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