Nickel-catalyzed highly chemoselective cocyclotrimerization of arynes with allenes: a novel method for 10-methylene-9,10-dihydrophenanthrenes

Literature Information

Publication Date 2004-02-04
DOI 10.1039/B315795D
Impact Factor 6.222
Authors

Jen-Chieh Hsieh, Dinesh Kumar Rayabarapu, Chien-Hong Cheng


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Abstract

The NiBr2(dppe)–Zn system effectively catalyzes the [2+2+2] cocyclotrimerization of arynes with allenes, leading to 10-methylene-9,10-dihydrophenanthrenes in moderate to good yields. The cocyclotrimerization is highly selective with only the internal double bond of the allenes being involved in the reaction.

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