Ni(ii) Complexes containing chiral tridentate phosphines as new catalysts for the hydroamination of activated olefins

Literature Information

Publication Date 2002-11-25
DOI 10.1039/B210680A
Impact Factor 6.222
Authors

Luca Fadini, Antonio Togni


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Abstract

Ni(II) complexes containing chiral tridentate ferrocenyl phosphines (Ni(PPP)) have been found to efficiently catalyse the hydroamination of activated olefins with both anilines and aliphatic amines at r.t. (TON up to 71, TOF up to ca. 3 h−1, and enantioselectivities up to 69% ee).

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