Self-assembled, optically-active {naphthalene diimide}U{cucurbit[8]uril} ensembles in an aqueous environment

Literature Information

Publication Date 2021-06-02
DOI 10.1039/D1CP00659B
Impact Factor 3.676
Authors

Heather F. Higginbotham, Subashani Maniam, Tina Hsia, Lyle Isaacs, Steven J. Langford, Toby D. M. Bell


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Abstract

Naphthalene diimides (NDIs) are shown to arrange spontaneously co-facially with cucurbit[8]uril (CB[8]) in an aqueous environment through purely non-covalent interactions. The resultant 2 : 2 supramolecular complex of NDI and CB[8] is highly fluorescent (>30 times more than the constituent NDIs) due to the formation of NDI–NDI excimers within the supramolecular complex.

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Physical Chemistry Chemical Physics
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