Structural studies of V2O5–WO3 and WO3–V2O5 solid solutions
Literature Information
Powder X-ray diffraction, Fourier transform Raman spectroscopy, solid-state NMR and X-ray photoelectron spectroscopy were used to determine the composition and structure of a mixed oxide containing 10 mol% V2O5 and 90 mol% WO3. The parent sample consists of hybrid crystallites of a tungsta-bronze isostructural with tetragonal WO3 but containing atomic vanadium in the bulk of the crystals and V(III) in the surface region, and of small crystals of strongly reduced vanadia-like surface species (V2O5–x with x=0.42). Further thermal treatment causes progressive surface segregation of vanadium from the V2O5–WO3 solid solution, accompanied by the formation of a WO3–V2O5 solid solution and partial tetragonal–monoclinic structural transformation of the bronze.
Recommended Journals

Cellulose

Colloid Journal

Chinese Journal of Chemistry

Journal of the Indian Institute of Science

Biocatalysis and Biotransformation

Herald of the Russian Academy of Sciences

Bioorganic & Medicinal Chemistry Letters

Journal of Asian Natural Products Research

Polycyclic Aromatic Compounds

Heteroatom Chemistry
Related Literature
Ultrafast excited-state relaxation of a binuclear Ag(i) phosphine complex in gas phase and solution
S. V. Kruppa, F. Bäppler, W. Klopper, S. P. Walg, W. R. Thiel, R. Diller
DOI: 10.1039/C7CP04128D
Unusual cis-diprotonated forms and fluorescent aggregates of non-peripherally alkoxy-substituted metallophthalocyanines
P. Kasprzycki, L. Sobotta, S. Lijewski, M. Wierzchowski, T. Goslinski, J. Mielcarek, C. Radzewicz, P. Fita
DOI: 10.1039/C7CP04321J
Different natures of surface electronic transitions of carbon nanoparticles
A. Cayuela, M. L. Soriano, F. M. Gelardi, M. Cannas, M. Valcárcel, F. Messina
DOI: 10.1039/C7CP04548D
Silica nanoparticle monolayers on a macroion modified surface: formation mechanism and stability
M. Morga, Z. Adamczyk, D. Kosior
DOI: 10.1039/C7CP03876C
Elucidating the impact of A-site cation change on photocatalytic H2 and O2 evolution activities of perovskite-type LnTaON2 (Ln = La and Pr)
Maged F. Bekheet, Judy N. Hart, Junie Jhon M. Vequizo, Akira Yamakata, Kunio Yubuta, Aleksander Gurlo, Masashi Hasegawa, Kazunari Domen
DOI: 10.1039/C7CP03714G
Graphitic carbon coupled poly(anthraquinone) for proton shuttle flow-in-a-cell application
Selvam Mathi, Rudra Kumar, Rajaram K. Nagarale, Ashutosh Sharma
DOI: 10.1039/C6CP08419B
The excited-state decay mechanism of 2,4-dithiothymine in the gas phase, microsolvated surroundings, and aqueous solution
Bin-Bin Xie, Qian Wang, Wei-Wei Guo, Ganglong Cui
DOI: 10.1039/C7CP00478H
Modelling of the charge carrier mobility in disordered linear polymer materials
Petr Toman, Miroslav Menšík, Wojciech Bartkowiak, Jiří Pfleger
DOI: 10.1039/C6CP07789G
Polarity governed selective amplification of through plane proton shuttling in proton exchange membrane fuel cells
Manu Gautam, Mruthyunjayachari Chattanahalli Devendrachari, Ravikumar Thimmappa, Alagar Raja Kottaichamy, Shahid Pottachola Shafi, Pramod Gaikwad, Harish Makri Nimbegondi Kotresh, Musthafa Ottakam Thotiyl
DOI: 10.1039/C6CP07724B
Swollen micelles and alcohol–surfactant co-adsorption: structures and mechanisms from liquid- and solid-state 1H–1H NMR spectroscopy
Christian Totland, Anne Marit Blokhus
DOI: 10.1039/C6CP08506G
You might also like
What are the main uses of 4-Nitrophenyl phosphate disodium salt hexahydrate (CAS: 333338-18-4)?
4-Nitrophenyl phosphate disodium salt hexahydrate is primarily used as a substra...
What are the main uses of 2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4)?
2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4) is widely ...
How should 2-Fluoro-4-biphenylcarboxylic acid (CAS: 137045-30-8) be stored?
2-Fluoro-4-biphenylcarboxylic acid should be stored in a cool, dry place at room...
What industries use Prednisolone-21-Carboxylic Acid (CAS: 61549-70-0)?
Prednisolone-21-Carboxylic Acid is primarily used in the pharmaceutical industry...
How should 4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) be stored?
4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) should be stored in a co...
What industries use 4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8)?
4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8) i...
What regulatory guidelines apply to dehydropachymic acid (CAS: 77012-31-8)?
Dehydropachymic acid (CAS: 77012-31-8) is regulated by various agencies. It fall...
What is the market or research trend for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic acid (CAS: 898561-66-5)?
The market and research trends for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic aci...
How should 1,10-Phenanthroline-2,9-dicarbaldehyde (CAS: 57709-62-3) be stored?
1,10-Phenanthroline-2,9-dicarbaldehyde should be stored in a cool, dry place awa...
How is 5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate (CAS: 113952-21-9) typically synthesized?
5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate can be synt...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.




