Homogenous nickel-catalyzed chemoselective transfer hydrogenation of functionalized nitroarenes with ammonia–borane

Literature Information

Publication Date 2023-11-10
DOI 10.1039/D3CC05173K
Impact Factor 6.222
Authors

Chitrarekha Dewangan, Sandeep Kumawat, Tarun Bhatt, Kishore Natte


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Abstract

Homogeneous Ni-catalyzed highly selective transfer hydrogenation of nitroarenes was successfully established using NH3BH3 as a hydrogen source. A broad range of functional groups were selectively reduced to provide the corresponding anilines in good to high yields. Further, pharmaceutically active compounds can be prepared that would otherwise be challenging to access.

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