Isolation of the elusive [Ru(bipy)3]+: a key intermediate in photoredox catalysis
Literature Information
Samuel J. Horsewill, Chengyang Cao, Noah Dabney, Eric S. Yang, Stephen Faulkner, Daniel J. Scott
Photoredox catalysis has flourished in recent years, but due to its widespread utility applications have grown faster than mechanistic understanding. In this report we help to address this deficit by isolating and characterising one of the intermediates of the iconic photocatalyst [Ru(bipy)3]2+, and testing its initial photoreactivity towards common substrates.
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![1,10-bis(3,5-dimethylphenyl)-12-hydroxy-4,5,6,7-tetrahydroiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocine 12-oxide structure 1,10-bis(3,5-dimethylphenyl)-12-hydroxy-4,5,6,7-tetrahydroiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocine 12-oxide structure](https://static.chemtradehub.com/structs/141/1412439-82-7-b9a9.webp)