Kinetic and mechanistic insights into Ni-AlKIT-6 catalyzed ethylene oligomerization
Literature Information
Publication Date
2021-10-11
DOI
10.1039/D1RE00258A
Impact Factor
4.239
Authors
Remi Beucher, Vasile Hulea, Claudia Cammarano
View Original
Abstract
A kinetic study of the ethylene oligomerization on a mesoporous 2 wt% Ni-AlKIT-6 was performed in a fixed bed flow reactor. The temperature ranged from 40 to 120 °C, the inlet ethylene partial pressure from 0.1 to 2.0 MPa and the space velocity (WHSV) was between 37 and 240 h−1. The main products identified at low ethylene conversion were n-butenes (90%) and hexenes (9%). A coordination–insertion mechanism (Cossee–Arlman) was proposed to explain the formation of these primary products. An activation energy of 15.2 kJ mol−1 and a global kinetic order of 1.28 were determined. The experimental data suggest that the kinetically limiting step is the insertion of ethylene into the metal–alkyl bond.
Related Literature
Pushing up the magnetisation values for iron oxide nanoparticles via zinc doping: X-ray studies on the particle's sub-nano structure of different synthesis routes
Jan Żukrowski, Marcin Sikora, Olga Safonova, Aleksey Shmeliov, Valeria Nicolosi, Tim Granath, Maximilian Oppmann, Marion Straßer
2016-08-30
Paper
DOI: 10.1039/C6CP04221J
Shuttle inhibition by chemical adsorption of lithium polysulfides in B and N co-doped graphene for Li–S batteries
Fen Li, Yan Su
2016-08-12
Paper
DOI: 10.1039/C6CP04071C
Ultrafast electronic energy relaxation in a conjugated dendrimer leading to inter-branch energy redistribution
D. Ondarse-Alvarez, S. Kömürlü, A. E. Roitberg, G. Pierdominici-Sottile, S. Tretiak, S. Fernandez-Alberti, V. D. Kleiman
2016-08-09
Paper
DOI: 10.1039/C6CP04448D
A robust salt-tolerant superoleophobic aerogel inspired by seaweed for efficient oil–water separation in marine environments
Yuqi Li, Hui Zhang, Jiandong Zhuang, Lihui Chen
2016-07-26
Paper
DOI: 10.1039/C6CP04284H
Probing ligand-induced modulation of metallic states in small gold nanoparticles using conduction electron spin resonance
Anthony Cirri, Alexey Silakov, Lasse Jensen, Benjamin J. Lear
2016-08-25
Paper
DOI: 10.1039/C6CP02205G
Effect of chain microstructure on self-assembly and emulsification of amphiphilic poly(acrylic acid)-polystyrene copolymers
Ye Zhu, Chenglin Yi, Qiong Hu, Wei Wei, Xiaoya Liu
2016-08-30
Paper
DOI: 10.1039/C6CP04978H
Coronene-based metal–organic framework: a theoretical exploration
Chandrima Chakravarty, Bikash Mandal, Pranab Sarkar
2016-08-17
Paper
DOI: 10.1039/C6CP05495A
Experimental and computational studies of the roles of MgO and Zn in talc for the selective formation of 1,3-butadiene in the conversion of ethanol
Yoshihiro Hayashi, Sohta Akiyama, Akimitsu Miyaji, Yasumasa Sekiguchi, Yasuharu Sakamoto, Akinobu Shiga, To-ru Koyama, Ken Motokura, Toshihide Baba
2016-08-16
Paper
DOI: 10.1039/C6CP04171J
Photodissociation dynamics of dinitrite at 355 nm: initiation of a reactive pathway
Lingxuan Wang, Lily Zu
2016-08-17
Paper
DOI: 10.1039/C6CP03049A
The 3D [(Cu2Br2){μ-EtS(CH2)4SEt}]n material: a rare example of a coordination polymer exhibiting triplet–triplet annihilation
Antoine Bonnot, Paul-Ludovic Karsenti, Frank Juvenal, Christopher Golz, Carsten Strohmann, Daniel Fortin, Michael Knorr, Pierre D. Harvey
2016-08-25
Communication
DOI: 10.1039/C6CP04728A
You might also like
Compound Q&A
What precautions should be taken when handling lithium chloride hydrate (1:1:1) (CAS: 16712-20-2)?
When handling lithium chloride hydrate (1:1:1) (CAS: 16712-20-2), it is importan...
16712-20-2Lithium chloride hyd...
Compound Q&A
Is 4-(4H-1,2,4-Triazol-4-yl)piperidine (CAS: 690261-92-8) safe?
4-(4H-1,2,4-Triazol-4-yl)piperidine is generally considered safe for use in phar...
690261-92-84-(4H-1,2,4-Triazol-...
Compound Q&A
How should waste containing 1,3-Thiazole-2-carboxamide (CAS: 16733-85-0) be handled?
Waste containing 1,3-Thiazole-2-carboxamide (CAS: 16733-85-0) should be collecte...
16733-85-01,3-Thiazole-2-carbo...
Compound Q&A
What regulatory guidelines apply to 5-(Difluoromethyl)-2-fluorobenzonitrile (CAS: 934175-58-3)?
5-(Difluoromethyl)-2-fluorobenzonitrile (CAS: 934175-58-3) is subject to regulat...
934175-58-35-(Difluoromethyl)-2...
Compound Q&A
How is Methyl 3-acetamido-2-thiophenecarboxylate (CAS: 22288-79-5) typically synthesized?
Methyl 3-acetamido-2-thiophenecarboxylate can be synthesized by the reaction of ...
22288-79-5Methyl 3-acetamido-2...
Compound Q&A
What is 4-Isoquinolinecarbonitrile (CAS: 34846-65-6)?
4-Isoquinolinecarbonitrile is a chemical compound with the CAS number 34846-65-6...
34846-65-64-Isoquinolinecarbon...
Compound Q&A
How should Methyl 1H-1,2,3-triazole-4-carboxylate (CAS: 877309-59-6) be stored?
Store Methyl 1H-1,2,3-triazole-4-carboxylate (CAS: 877309-59-6) in a cool, dry p...
877309-59-6Methyl 1H-1,2,3-tria...
Compound Q&A
What regulatory guidelines apply to 6-Bromo[1,3]thiazolo[5,4-b]pyridin-2-amine (CAS: 1160791-13-8)?
6-Bromo[1,3]thiazolo[5,4-b]pyridin-2-amine (CAS: 1160791-13-8) is subject to the...
1160791-13-86-Bromo[1,3]thiazolo...
Compound Q&A
Is (2S,3S)-2-Ammonio-3-(3,4-dihydroxyphenyl)-3-hydroxypropanoate (CAS: 23651-95-8) safe?
(2S,3S)-2-Ammonio-3-(3,4-dihydroxyphenyl)-3-hydroxypropanoate (CAS: 23651-95-8) ...
23651-95-8(2S,3S)-2-Ammonio-3-...
Compound Q&A
What are the physical and chemical properties of 7-bromo-3-methyl-3,4-dihydroquinazolin-4-one (CAS: 1293987-84-4)?
7-Bromo-3-methyl-3,4-dihydroquinazolin-4-one is a solid with a crystalline form....
1293987-84-47-bromo-3-methyl-3,4...
Source Journal
Reaction Chemistry & Engineering
CiteScore:
0
Self-citation Rate:
8.8%
Articles per Year:
284
Reaction Chemistry & Engineering is an interdisciplinary journal reporting cutting-edge research focused on enhancing the understanding and efficiency of reactions. Reaction engineering leverages the interface where fundamental molecular chemistry meets chemical engineering and technology. Challenges in chemistry can be overcome by the application of new technologies, while engineers may find improved solutions for process development from the latest developments in reaction chemistry. Reaction Chemistry & Engineering is a unique forum for researchers whose interests span the broad areas of chemical engineering and chemical sciences to come together in solving problems of importance to wider society. All papers should be written to be approachable by readers across the engineering and chemical sciences. Papers that consider multiple scales, from the laboratory up to and including plant scale, are particularly encouraged.
Recommended Compounds
![6-(Benzyloxy)-8-(2-bromoacetyl)-2H-benzo[b][1,4]oxazin-3(4H)-one structure](https://static.chemtradehub.com/structs/926/926319-53-1-2287.webp "6-(Benzyloxy)-8-(2-bromoacetyl)-2H-benzo[b][1,4]oxazin-3(4H)-one structure")
6-(Benzyloxy)-8-(2-bromoacetyl)-2H-benzo[b][1,4]oxazin-3(4H)-one
CAS Number:
926319-53-1
Molecular Formula:
C17H14BrNO4
![6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde structure](https://static.chemtradehub.com/structs/564/564-94-3-e746.webp "6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde structure")
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.