Photodissociation dynamics of dinitrite at 355 nm: initiation of a reactive pathway

Literature Information

Publication Date 2016-08-17
DOI 10.1039/C6CP03049A
Impact Factor 3.676
Authors

Lingxuan Wang, Lily Zu


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Abstract

Dinitrites are effective nitrosating reagents in preparative chemistry and their decomposition products are involved in the atmospheric reaction of volatile organic compounds with nitrogen oxides (NOx). In this work, photodissociation dynamics of five alkyl dinitrites were investigated by detecting the LIF spectra of the dissociation products and theoretical calculations. The results showed that the C–C bond connecting the two nitrosooxy (–ONO) functional groups was the weakest bond in vicinal dinitrites and aldehydes were the dissociation products. For dinitrites with two ONO groups separated by a CH2 group, vinoxy and 1-methylvinoxy radicals were detected as the fragments via photodissociation, indicating a different mechanism compared to thermal decomposition. This observation demonstrated that a new reactive pathway could be initiated by photolysis of dinitrites.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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