Reversible cyclic-linear topological transformation using a long-range rotaxane switch

Literature Information

Publication Date 2021-10-07
DOI 10.1039/D1PY01197A
Impact Factor 5.582
Authors

Daisuke Aoki, Gota Aibara


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Abstract

A reversible cyclic-linear topological transformation of a poly(ε-caprolactone) facilitated by a long-range rotaxane switch is reported. A linear polymer, whose topology is fixed by a protonated tert-amine/crown ether interaction at the center of the polymer chain, was reversibly transformed into a cyclic polymer fixed by urethane linkage/crown ether interaction at the polymer end upon neutralization/acidification of the tert-amine moiety.

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Polymer Chemistry
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