![(1R,3S,5R)-2-{[(2-Methyl-2-propanyl)oxy]carbonyl}-2-azabicyclo[3.1.0]hexane-3-carboxylic acid structure](https://static.chemtradehub.com/structs/197/197142-34-0-6a44.webp "(1R,3S,5R)-2-{[(2-Methyl-2-propanyl)oxy]carbonyl}-2-azabicyclo[3.1.0]hexane-3-carboxylic acid structure")
(1R,3S,5R)-2-{[(2-Methyl-2-propanyl)oxy]carbonyl}-2-azabicyclo[3.1.0]hexane-3-carboxylic acid
CAS Number:
197142-34-0
Molecular Formula:
C11H17NO4
Cationic polymerization of vinyl monomers using halogen bonding organocatalysts with varied activity
Literature Information
Publication Date
2020-10-09
DOI
10.1039/D0PY01207F
Impact Factor
5.582
Authors
Koji Takagi, Hiroto Murakata, Koji Yamauchi, Kohei Hashimoto
View Original
Abstract
By using non-ionic and multidentate halogen bonding organocatalysts, the cationic polymerization of IBVE was investigated to reveal the relationship between the catalytic activity and the substitution pattern of halogen bond donor units with the aid of theoretical calculation. The polymerization successfully proceeded at room temperature using an appropriate catalyst. The polymerization of other vinyl ethers and styrene derivatives was also investigated in the presence of ionic organocatalysts to figure out that the coordination ability of the counter anion significantly affected the catalytic activity. In particular, the polymerization of pMOS occurred in a controlled manner enabling the molecular weight regulation by ca. Mn = 10 000.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
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2,5,8,11,14,17,20,23,26,29,32-Undecaoxatetratriacontan-34-amine
CAS Number:
854601-60-8
Molecular Formula:
C23H49NO11
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