Facile synthesis of optically active helical poly(phenyl isocyanide) brushes on a silicon surface and their chiral resolution ability

Literature Information

Publication Date 2018-02-28
DOI 10.1039/C8PY00097B
Impact Factor 5.582
Authors

Ben-Fa Chu, Jia-Hong Chu, Song-Qing Zhao, Na Liu, Zong-Quan Wu


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Abstract

Optically active helical poly(phenyl isocyanide)s were grafted onto a silicon wafer. The obtained polymer brushes possessed abundant chiral microenvironments originating from the chirality of the helical arms. Such chiral materials exhibited excellent chiral resolution ability. The enantiomeric excess value of the absorbed mode compound was up to 87%.

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Polymer Chemistry

Polymer Chemistry
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