The partial molar volumes of some tetra- and pentapeptides in aqueous solution: a test of amino acid side-chain group additivity for unfolded proteins
Literature Information
Marko Häckel, Hans-Jürgen Hinz, Gavin R. Hedwig
Ten new peptides with the amino acid sequences glycyl-X-Y-glycine and glycyl-X-Y-Z-glycine, where X, Y and Z are amino acids with neutral side-chains, have been synthesized and the partial molar volumes at infinite dilution, V2°, have been determined for all these peptides in aqueous solution at 298.15 K. For several of the peptides, V2° data have also been obtained over the temperature range 283.15 to 363.15 K using a scanning densimetric method. The V2° results obtained are compared with those calculated using the principle of group additivity and the group partial molar volumes we have derived in earlier work. We have shown that our group partial molar volumes can be used to reliably predict the partial molar volumes over a wide temperature range of polypeptides that have neutral amino acid side-chains.
Related Literature
Self-organized formation of a hierarchical self-similar structure with calcium carbonate
Hiroaki Imai, Tomohiro Terada, Satoshi Yamabi
DOI: 10.1039/B211240J
Asymmetric protonation of lithium enolates of α-amino acid derivatives with α-amino acid-based chiral Brønsted acids
Kentaro Futatsugi, Akira Yanagisawa, Hisashi Yamamoto
DOI: 10.1039/B211523A
Synthesis and characterization of highly ordered functional mesoporous silica thin films with positively chargeable –NH2 groups
Nanguo Liu, Roger A. Assink, Bernd Smarsly
DOI: 10.1039/B301910A
Preparation of ZnO nanocrystalsvia ultrasonic irradiation
Dong Qian, J.Z. Jiang, Poul Lenvig Hansen
DOI: 10.1039/B301504A
Soluble polymer-supported convergent parallel library synthesis
Jung-Mo Ahn, Paul Wentworth Jr., Kim D. Janda
DOI: 10.1039/B210696E
Reductive cleavage of the C–O bond of acetals and orthoesters: reduction by silane in the presence of a Rh–PPh3 complex
Tetsuo Ohta, Tsugumi Michibata, Kazuyuki Yamada, Ryohei Omori, Isao Furukawa
DOI: 10.1039/B302124F
Pyridine–sugar conjugates as potent inhibitors of enzyme-catalysed glycosidehydrolysis
Peter A. Nkansah, Alan H. Haines, N. Patrick J. Stamford
DOI: 10.1039/B211399F
A new organic superconductor, (DODHT)2BF4·H2O
Hiroyuki Nishikawa, Asami Machida, Takanobu Morimoto, Koichi Kikuchi, Takeshi Kodama, Isao Ikemoto, Jun-ichi Yamada, Harukazu Yoshino, Keizo Murata
DOI: 10.1039/B211275B
High temperature synthesis of a noncentrosymmetric site-ordered cobalt aluminophosphate related to the pollucite structure
P. Bishop
DOI: 10.1039/B300037K
Photoluminescent supramolecular networks from metal-mediated assembly of polythia conjugated dieneyne
Yuan-Te Fu, Vincent M. Lynch, Richard J. Lagow
DOI: 10.1039/B212789J
You might also like
What precautions should be taken when handling 4-(2-Furylmethyl)thiomorpholine 1,1-dioxide (CAS: 79206-94-3)?
When handling 4-(2-Furylmethyl)thiomorpholine 1,1-dioxide (CAS: 79206-94-3), it ...
What precautions should be taken when handling 4-Chloro-N-[2-(4-morpholinyl)ethyl]benzamide (CAS: 71320-77-9)?
When handling 4-Chloro-N-[2-(4-morpholinyl)ethyl]benzamide (CAS: 71320-77-9), it...
How should waste containing 2-[2-(2-Methoxyethoxy)ethoxy]ethyl 4-methylbenzenesulfonate (CAS: 62921-74-8) be handled?
Waste containing this compound (CAS: 62921-74-8) should be handled according to ...
How should waste containing (S)-Methyl 2-amino-3-cyclohexylpropanoate be handled?
Waste containing (S)-Methyl 2-amino-3-cyclohexylpropanoate should be collected i...
How is 5-({4-[(2S,4R)-4-Hydroxy-2-methyltetrahydro-2H-pyran-4-yl]-2-thienyl}sulfanyl)-1-methyl-1,3-dihydro-2H-indol-2-one (CAS: 166882-70-8) typically synthesized?
This compound can be synthesized using a multi-step process involving the conjug...
Are there alternatives to (2E)-3-(3,4-Dichlorophenyl)acrylic acid (CAS: 7312-27-8) in synthesis?
There are several alternatives to (2E)-3-(3,4-Dichlorophenyl)acrylic acid in syn...
How should Ethyl 6-(2-nitrophenyl)imidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 925437-84-9) be stored?
Ethyl 6-(2-nitrophenyl)imidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 925437-84...
How should waste containing 2-(1,3-Thiazol-2-yl)ethanamine (CAS: 18453-07-1) be handled?
Waste containing 2-(1,3-Thiazol-2-yl)ethanamine (CAS: 18453-07-1) should be coll...
How is Methyl 5-iodo-2-methylbenzoate (CAS: 103440-54-6) typically synthesized?
Methyl 5-iodo-2-methylbenzoate can be synthesized through the iodination of meth...
How is 5-Chloro[1,2,4]triazolo[1,5-a]pyridine (CAS: 1427399-34-5) typically synthesized?
5-Chloro[1,2,4]triazolo[1,5-a]pyridine is commonly synthesized via the condensat...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.











![1,2-Diphenyl-4-[2-(phenylsulfinyl)ethyl]-3,5-pyrazolidinedione structure 1,2-Diphenyl-4-[2-(phenylsulfinyl)ethyl]-3,5-pyrazolidinedione structure](https://static.chemtradehub.com/structs/57-/57-96-5-efcc.webp)


