Ultrafast IR laser control of photodissociation: single- vs. multi-pulse schemes

Literature Information

Publication Date
DOI 10.1039/A902136A
Impact Factor 3.676
Authors


View Original

Abstract

Analytical laser pulses are designed to break the H–Co bond of HCo(CO)4 in the electronic ground state. The potential energy surface is taken from a pseudo-triatomic model of this compound. Single- and two-pulse dissociations are shown to be equally efficient in their ability to dissociate the molecule within two picoseconds at moderate field strengths. The isotope TCo(CO)4 is considered as well and results of a three-pulse laser interaction are presented. Laser selective isotope separation is demonstrated to be feasible over a wide range of frequencies using a single driving field.

Related Literature

Structure and magnetism of the first strictly dinuclear compound containing paramagnetic 3d and 5f metal ions. Major influence of the CuII ion coordination on the exchange CuII–UIV interaction

Lionel Salmon, Pierre Thuéry, Eric Rivière, Jean-Jacques Girerd, Michel Ephritikhine

2003-02-25 Communication

DOI: 10.1039/B212635D

Towards “designer” surfaces: functionalisation of self-assembled monolayer (SAM) on colloidal gold by alkene metathesis‡

Debasis Samanta, Nicolas Faure, Francis Rondelez, Amitabha Sarkar

2003-04-16 Communication

DOI: 10.1039/B300833A

Beta zeolite supported on silicon carbide for Friedel–Crafts fixed-bed reactions

Gauthier Winé, Joseph Matta, Jean-Philippe Tessonnier, Cuong Pham-Huu, Marc-Jacques Ledoux

2003-01-16 Communication

DOI: 10.1039/B209858J

A novel bioassay for screening and quantification of taxanes

Sergi Morais, P. C. Pandey, Wilfred Chen, Ashok Mulchandani

2003-04-17 Communication

DOI: 10.1039/B302112B

A novel access to 3-aryl-2-norbornyl cation

2003-02-25 Communication

DOI: 10.1039/B300839H

Effect of water on the catalytic behaviour of VPO in the selective oxidation of propane to acrylic acid

G. Landi, L. Lisi, J. C. Volta

2003-01-23 Communication

DOI: 10.1039/B211619G

Zn-Proline catalyzed direct aldol reaction in aqueous media

Tamis Darbre, Miguel Machuqueiro

2003-03-31 Communication

DOI: 10.1039/B301117H

Kumada–Corriu coupling of Grignard reagents, probed with a chiral Grignard reagent

Bettina Hölzer, Reinhard W. Hoffmann

2003-02-19 Communication

DOI: 10.1039/B300033H

Systematic manipulation of surface chemical reaction on the nanoscale: a novel approach for constructing three-dimensional nanostructures

Xiuzhu Wang, Dejian Zhou, Trevor Rayment, Chris Abell

2003-01-20 Communication

DOI: 10.1039/B211906D

Non-covalent switch for intramolecular energy transfer

Joe Otsuki, Akane Yasuda, Toshio Takido

2003-02-05 Communication

DOI: 10.1039/B212912D

You might also like

Compound Q&A

What precautions should be taken when handling 4-(2-Furylmethyl)thiomorpholine 1,1-dioxide (CAS: 79206-94-3)?

When handling 4-(2-Furylmethyl)thiomorpholine 1,1-dioxide (CAS: 79206-94-3), it ...

79206-94-34-(2-Furylmethyl)thi...
Compound Q&A

What precautions should be taken when handling 4-Chloro-N-[2-(4-morpholinyl)ethyl]benzamide (CAS: 71320-77-9)?

When handling 4-Chloro-N-[2-(4-morpholinyl)ethyl]benzamide (CAS: 71320-77-9), it...

71320-77-94-Chloro-N-[2-(4-mor...
Compound Q&A

How should waste containing 2-[2-(2-Methoxyethoxy)ethoxy]ethyl 4-methylbenzenesulfonate (CAS: 62921-74-8) be handled?

Waste containing this compound (CAS: 62921-74-8) should be handled according to ...

62921-74-82-[2-(2-Methoxyethox...
Compound Q&A

How should waste containing (S)-Methyl 2-amino-3-cyclohexylpropanoate be handled?

Waste containing (S)-Methyl 2-amino-3-cyclohexylpropanoate should be collected i...

40056-18-6(S)-Methyl 2-amino-3...
166882-70-85-({4-[(2S,4R)-4-Hyd...
Compound Q&A

Are there alternatives to (2E)-3-(3,4-Dichlorophenyl)acrylic acid (CAS: 7312-27-8) in synthesis?

There are several alternatives to (2E)-3-(3,4-Dichlorophenyl)acrylic acid in syn...

7312-27-8(2E)-3-(3,4-Dichloro...
Compound Q&A

How should Ethyl 6-(2-nitrophenyl)imidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 925437-84-9) be stored?

Ethyl 6-(2-nitrophenyl)imidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 925437-84...

925437-84-9Ethyl 6-(2-nitrophen...
Compound Q&A

How should waste containing 2-(1,3-Thiazol-2-yl)ethanamine (CAS: 18453-07-1) be handled?

Waste containing 2-(1,3-Thiazol-2-yl)ethanamine (CAS: 18453-07-1) should be coll...

18453-07-12-(1,3-Thiazol-2-yl)...
Compound Q&A

How is Methyl 5-iodo-2-methylbenzoate (CAS: 103440-54-6) typically synthesized?

Methyl 5-iodo-2-methylbenzoate can be synthesized through the iodination of meth...

103440-54-6Methyl 5-iodo-2-meth...
Compound Q&A

How is 5-Chloro[1,2,4]triazolo[1,5-a]pyridine (CAS: 1427399-34-5) typically synthesized?

5-Chloro[1,2,4]triazolo[1,5-a]pyridine is commonly synthesized via the condensat...

1427399-34-55-Chloro[1,2,4]triaz...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.