![(2S)-2-{[(9H-Fluoren-9-ylmethoxy)carbonyl]amino}-4-(methylselanyl)butanoic acid structure](https://static.chemtradehub.com/structs/121/1217852-49-7-f252.webp "(2S)-2-{[(9H-Fluoren-9-ylmethoxy)carbonyl]amino}-4-(methylselanyl)butanoic acid structure")
(2S)-2-{[(9H-Fluoren-9-ylmethoxy)carbonyl]amino}-4-(methylselanyl)butanoic acid
CAS Number:
1217852-49-7
Molecular Formula:
C20H21NO4Se
Direct synthesis of hydrazones by visible light mediated aerobic oxidative cleavage of the CC bond
Literature Information
Publication Date
2017-05-15
DOI
10.1039/C7QO00276A
Impact Factor
5.281
Authors
Ya Ding, Hao Li, Yunge Meng, Te Zhang, Jiawen Li, Qiu-Yun Chen
View Original
Abstract
A metal-free protocol through visible light mediated oxidative cleavage of CC bonds to directly construct CN bonds has been developed for the conversion of alkenes to hydrazones under mild conditions. The reaction involves a diazetidine intermediate that is generated by [2 + 2] annulation of alkenes with diazenes generated in situ by single-electron oxidation of arylhydrazines. The key features of this reaction include a broad substrate scope and readily available reagents.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
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N,N-Dimethyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2-pyrimidinamine
CAS Number:
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Molecular Formula:
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