![[(1S,2S,3R,4S,7R,9S,10S,12R,15S)-4,12-Diacetyloxy-15-[(2R,3S)-3-benzamido-3-phenyl-2-(2,2,2-trichloroethoxycarbonyloxy)propanoyl]oxy-1,9-dihydroxy-10,14,17,17-tetramethyl-11-oxo-6-oxatetracyclo[11.3.1.03,10.04,7]heptadec-13-en-2-yl] benzoate structure](https://static.chemtradehub.com/structs/100/100431-55-8-7104.webp "[(1S,2S,3R,4S,7R,9S,10S,12R,15S)-4,12-Diacetyloxy-15-[(2R,3S)-3-benzamido-3-phenyl-2-(2,2,2-trichloroethoxycarbonyloxy)propanoyl]oxy-1,9-dihydroxy-10,14,17,17-tetramethyl-11-oxo-6-oxatetracyclo[11.3.1.03,10.04,7]heptadec-13-en-2-yl] benzoate structure")
Copolymers of carbazole and phenazine derivatives: minor structural modification, but totally different photodetector performance
Literature Information
Publication Date
2016-12-21
DOI
10.1039/C6PY01733A
Impact Factor
5.582
Authors
Shuang Li, Xianyu Deng, Lei Feng, Xincheng Miao, Kuangyi Tang, Qianqian Li, Zhen Li
View Original
Abstract
With the aim to explore the relationship between the structure of conjugated polymers and the performance of their corresponding photodetectors, four donor–acceptor type conjugated polymers were designed and prepared through the convenient Suzuki coupling reaction, in which the structure of the acceptor group, phenazine moieties, changed with different planar π-systems from small to a little bigger, accompanied with a subtly adjusted HOMO and LUMO. The fabricated photodetectors of these four polymers confirmed that the minor structural difference would lead to very different device performance, with the highest photodetectivity, up to 6.2 × 1012 Jones, and the fastest rise time of 160 μs.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
2,2-dideuterio-2-(3,4,5,6-tetradeuterio-2-pyridyl)acetic acid;hydrochloride
CAS Number:
1329799-67-8
Molecular Formula:
C7H2ClD6NO2
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