ADMET polymerization of α,ω-unsaturated glycolipids: synthesis and physico-chemical properties of the resulting polymers

Literature Information

Publication Date 2017-05-31
DOI 10.1039/C7PY00788D
Impact Factor 5.582
Authors

D. Pintori


View Original

Abstract

Trehalose diesters exhibiting α,ω-unsaturation are glycolipids which can be easily polymerized by ADMET (acyclic diene metathesis) polymerization. In this paper, enzymatic esterification was performed to selectively esterify primary hydroxyl groups of trehalose (6 and 6′-positions) with vinyl undecenoate. The vinyl ester was beforehand obtained by palladium-catalyzed transesterification of undecenoic acid with vinyl acetate. The resulting trehalose diundecenoate was homopolymerized and copolymerized with undecenyl undecenoate in order to obtain random copolymers with different compositions. The synthesis of such copolymers was confirmed by 1H NMR spectroscopy and size exclusion chromatography (SEC). Their solid-state phase separation was investigated by DSC and X-ray scattering as a function of temperature and their solution self-assembly was investigated by dynamic light scattering (DLS) in water.

Related Literature

Enhancement of facilitated olefin transport by amino acid in silver–polymer complex membranes

Sang Wook Kang, Jong Hak Kim, Jongok Won, Kookheon Char, Yong Soo Kang

2003-02-25 Communication

DOI: 10.1039/B211933A

Construction of extended networks with a trimeric pyrazole synthon

Ishtvan Boldog, Eduard B. Rusanov, Joachim Sieler, Steffen Blaurock, Konstantin V. Domasevitch

2003-02-25 Communication

DOI: 10.1039/B212540D

Pyridine–sugar conjugates as potent inhibitors of enzyme-catalysed glycosidehydrolysis

Peter A. Nkansah, Alan H. Haines, N. Patrick J. Stamford

2003-02-20 Communication

DOI: 10.1039/B211399F

A highly sensitive and selective fluorescent molecular sensor for Pb(ii) based on a calix[4]arene bearing four dansyl groups

Rémi Métivier, Isabelle Leray, Bernard Valeur

2003-03-26 Communication

DOI: 10.1039/B301323E

Soluble polymer-supported convergent parallel library synthesis

Jung-Mo Ahn, Paul Wentworth Jr., Kim D. Janda

2003-01-27 Communication

DOI: 10.1039/B210696E

Formation and destruction of the guanine quartet in solution observed by cold-spray ionization mass spectrometry

Shigeru Sakamoto, Isao Saito

2003-02-17 Communication

DOI: 10.1039/B212432G

Effect of water on the catalytic behaviour of VPO in the selective oxidation of propane to acrylic acid

G. Landi, L. Lisi, J. C. Volta

2003-01-23 Communication

DOI: 10.1039/B211619G

Synthesis of a η2-2,3-diphosphabutadiene complex of zerovalent platinum from the corresponding η2-phosphaalkyne complex

Maria Helena Araujo, Peter B. Hitchcock, John F. Nixon, Uwe Kuehner, Othmar Stelzer

2003-04-02 Communication

DOI: 10.1039/B301335A

Polyoxometalate-catalysed epoxidation of 1-octene with hydrogen peroxide in microemulsions coupled with ultrafiltration

Arnold Lambert, Pawel Plucinski, Ivan V. Kozhevnikov

2003-02-17 Communication

DOI: 10.1039/B300494P

You might also like

Compound Q&A

What precautions should be taken when handling 4-(2-Furylmethyl)thiomorpholine 1,1-dioxide (CAS: 79206-94-3)?

When handling 4-(2-Furylmethyl)thiomorpholine 1,1-dioxide (CAS: 79206-94-3), it ...

79206-94-34-(2-Furylmethyl)thi...
Compound Q&A

What precautions should be taken when handling 4-Chloro-N-[2-(4-morpholinyl)ethyl]benzamide (CAS: 71320-77-9)?

When handling 4-Chloro-N-[2-(4-morpholinyl)ethyl]benzamide (CAS: 71320-77-9), it...

71320-77-94-Chloro-N-[2-(4-mor...
Compound Q&A

How should waste containing 2-[2-(2-Methoxyethoxy)ethoxy]ethyl 4-methylbenzenesulfonate (CAS: 62921-74-8) be handled?

Waste containing this compound (CAS: 62921-74-8) should be handled according to ...

62921-74-82-[2-(2-Methoxyethox...
Compound Q&A

How should waste containing (S)-Methyl 2-amino-3-cyclohexylpropanoate be handled?

Waste containing (S)-Methyl 2-amino-3-cyclohexylpropanoate should be collected i...

40056-18-6(S)-Methyl 2-amino-3...
166882-70-85-({4-[(2S,4R)-4-Hyd...
Compound Q&A

Are there alternatives to (2E)-3-(3,4-Dichlorophenyl)acrylic acid (CAS: 7312-27-8) in synthesis?

There are several alternatives to (2E)-3-(3,4-Dichlorophenyl)acrylic acid in syn...

7312-27-8(2E)-3-(3,4-Dichloro...
Compound Q&A

How should Ethyl 6-(2-nitrophenyl)imidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 925437-84-9) be stored?

Ethyl 6-(2-nitrophenyl)imidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 925437-84...

925437-84-9Ethyl 6-(2-nitrophen...
Compound Q&A

How should waste containing 2-(1,3-Thiazol-2-yl)ethanamine (CAS: 18453-07-1) be handled?

Waste containing 2-(1,3-Thiazol-2-yl)ethanamine (CAS: 18453-07-1) should be coll...

18453-07-12-(1,3-Thiazol-2-yl)...
Compound Q&A

How is Methyl 5-iodo-2-methylbenzoate (CAS: 103440-54-6) typically synthesized?

Methyl 5-iodo-2-methylbenzoate can be synthesized through the iodination of meth...

103440-54-6Methyl 5-iodo-2-meth...
Compound Q&A

How is 5-Chloro[1,2,4]triazolo[1,5-a]pyridine (CAS: 1427399-34-5) typically synthesized?

5-Chloro[1,2,4]triazolo[1,5-a]pyridine is commonly synthesized via the condensat...

1427399-34-55-Chloro[1,2,4]triaz...

Source Journal

Polymer Chemistry

Polymer Chemistry
CiteScore: 8.6
Self-citation Rate: 7.3%
Articles per Year: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.