Synthesis, spectral and electrochemical investigations of bichromophoric pentads possessing tetraazaporphyrin and (bipy)2RuII/(phen)2RuII moieties

Literature Information

Publication Date 2003-01-27
DOI 10.1039/B209812A
Impact Factor 6.222
Authors

Rajendra Prasad, Elisa Murguly, Neil R. Branda


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Abstract

Four (bipy)2RuII and (phen)2RuII moieties have been attached to the magnesium tepraazaporphyrin periphery by exploiting thioether coordination to obtain pentads 1 and 2 respectively. These molecules exhibit strong inter-chromophore electronic interaction as reflected by the changes in their spectral and oxidation potential shifts.

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