Synthesis, spectral and electrochemical investigations of bichromophoric pentads possessing tetraazaporphyrin and (bipy)2RuII/(phen)2RuII moieties
Literature Information
Rajendra Prasad, Elisa Murguly, Neil R. Branda
Four (bipy)2RuII and (phen)2RuII moieties have been attached to the magnesium tepraazaporphyrin periphery by exploiting thioether coordination to obtain pentads 1 and 2 respectively. These molecules exhibit strong inter-chromophore electronic interaction as reflected by the changes in their spectral and oxidation potential shifts.
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