Synthesis of a η2-2,3-diphosphabutadiene complex of zerovalent platinum from the corresponding η2-phosphaalkyne complex
Literature Information
Maria Helena Araujo, Peter B. Hitchcock, John F. Nixon, Uwe Kuehner, Othmar Stelzer
Hydrozirconation of the η2-phosphaalkyne complex [Pt(dppe)(η2-tBuCP)] with [ZrHCl(η5-C5H5)2], followed by treatment with the chlorophosphaalkene ClPC(SiMe3)2 affords the η2-2,3-diphosphabutadiene complex [Pt(dppe)(η2-tBuC(H)PPC(SiMe3)2]. In the presence of [Pt(PPh3)2] the latter undergoes an addition reaction with water to afford the structurally characterised Pt(II) complex [Pt(dppe)(tBuCH2P(O)HPC(SiMe3)2]
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