A magnetooptical study of (4-(2-dibutylaminoethanolato-N,O,O,O) chlorido copper(ii)): a cubane complex with dominant ferromagnetic interactions

Literature Information

Publication Date 2015-10-20
DOI 10.1039/C5CP05836H
Impact Factor 3.676
Authors

Serghei M. Ostrovsky, Zbigniew Tomkowicz, Wolfgang Haase


View Original

Abstract

This paper reports the experimental and theoretical study of a tetranuclear (CuClOCH2CH2N(C4H9)2)4 complex. Analysis of the magnetic circular dichroism spectrum was performed based on the Hamiltonian that includes the crystal field of the nearest ligands and the spin–orbit interaction. The crystal field parameters were evaluated in the framework of the exchange charge model that accounts for the exchange and covalence effects. The values of the crystal field parameters obtained during the analysis of the magnetic circular dichroism spectrum were used for the calculation of the principal values and the directions of the principal axes of the local g-tensors and for the simulation of both temperature dependence of the magnetic susceptibility and field dependence of the magnetization. The value of the exchange parameter (Jex = 30 cm−1) was obtained. It was demonstrated that the description of the low temperature magnetic properties requires taking into account the intercluster interaction.

Related Literature

Inside front cover

Cover

DOI: 10.1039/C8AN90085J

Rapid determination of binding parameters of chitin binding domains using chitin-coated quartz crystal microbalance sensor chips

Stephan Vogt, Marco Kelkenberg, Tanja Nöll, Benedikt Steinhoff, Holger Schönherr, Hans Merzendorfer, Gilbert Nöll

2018-09-25 Paper

DOI: 10.1039/C8AN01453A

Raman spectroscopy in microsurgery: impact of operating microscope illumination sources on data quality and tissue classification

Joannie Desroches, Audrey Laurence, Michael Pinto, Marie-Andrée Tremblay, Kevin Petrecca, Frédéric Leblond

2016-10-31 Paper

DOI: 10.1039/C6AN02061E

Effects of nilotinib on leukaemia cells using vibrational microspectroscopy and cell cloning

M. R. Siddique, A. V. Rutter, K. Wehbe, G. Cinque, G. Bellisola

2016-12-08 Paper

DOI: 10.1039/C6AN01914E

Microcontact printing with aminosilanes: creating biomolecule micro- and nanoarrays for multiplexed microfluidic bioassays

Shivani Sathish, Sébastien G. Ricoult, Kazumi Toda-Peters, Amy Q. Shen

2017-04-05 Paper

DOI: 10.1039/C7AN00273D

Structuring polarity-inverted TBA to G-quadruplex for selective recognition of planarity of natural isoquinoline alkaloids

Yufeng Zhou, Yali Yu, Longlong Gao, Yifan Fei, Ting Ye, Qiusha Li, Xiaoshun Zhou, Ning Gan, Yong Shao

2018-08-28 Paper

DOI: 10.1039/C8AN01561A

Detection of Escherichia coli bacteria by impact electrochemistry

Rosa A. S. Couto, Lifu Chen, Sabine Kuss, Richard G. Compton

2018-09-17 Communication

DOI: 10.1039/C8AN01675E

Fully convolutional neural network for removing background in noisy images of uranium bearing particles

Jay G. Tarolli, Benjamin E. Naes, Lamar Butler, Keeyahna Foster, Caleb M. Gumbs, Andrea L. Howard, David Willingham

2017-03-31 Paper

DOI: 10.1039/C7AN00175D

You might also like

Compound Q&A

What is the market or research trend for N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0)?

N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0) is increasingly being used ...

52818-63-0N-(4-Methoxybenzyl)-...
Compound Q&A

What precautions should be taken when handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate (CAS: 1050507-06-6)?

When handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate, appropriate p...

1050507-06-6Ethyl 4-(2-chlorophe...
Compound Q&A

What regulatory guidelines apply to diethyldiselane (CAS: 628-39-7)?

Diethyldiselane (CAS: 628-39-7) is classified under the Globally Harmonized Syst...

628-39-7Diethyldiselane
Compound Q&A

What is the market or research trend for oxocopper (CAS: 12053-18-8)?

The market for oxocopper (CAS: 12053-18-8) is primarily driven by its use in cat...

12053-18-8oxocopper; oxo-(oxoc...
Compound Q&A

What is the market or research trend for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-carboxylic acid?

The market for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-c...

1268519-54-55-{[(2-Methyl-2-prop...
Compound Q&A

What is 2-(1-Pyrrolidinyl)-4-pyridinamine (CAS: 35981-63-6)?

2-(1-Pyrrolidinyl)-4-pyridinamine is a chemical compound with the CAS number 359...

35981-63-62-(1-Pyrrolidinyl)-4...
Compound Q&A

What are the physical and chemical properties of 2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1)?

2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1) is a crystalline sol...

91556-75-12-(3-Pyridinyl)-1-az...
Compound Q&A

How is (S)-Alpha-allyl-proline hydrochloride (CAS: 129704-91-2) typically synthesized?

(S)-Alpha-allyl-proline hydrochloride is usually synthesized via a Wittig reacti...

129704-91-2(S)-Alpha-allyl-prol...
Compound Q&A

What is 3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5)?

3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5) is an organic compound w...

4857-42-53-Methyl-1,2-oxazole...
Compound Q&A

How is Lys-SMCC-DM1 (CAS: 1281816-04-3) typically synthesized?

Lys-SMCC-DM1 is synthesized via a multi-step process involving the coupling of S...

1281816-04-3Lys-SMCC-DM1

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.