The growth of single crystal silver wires at the nitrobenzene|water interface

Literature Information

Publication Date 2011-06-01
DOI 10.1039/C0CP01469A
Impact Factor 3.676
Authors

Ulrich Hasse, Gottfried J. Palm, Winfried Hinrichs, Fritz Scholz


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Abstract

Single crystal silver wires can be grown at the nitrobenzene|water interface when silver ions dissolved in the aqueous phase are reduced by decamethyl ferrocene dissolved in the nitrobenzene phase. The successful growth of these wires depends on a number of experimental conditions, most prominently on the concentration ratio of reactants, nucleation rates, shape of formed nuclei, and wettability of nuclei. The size–time dependence can be modeled on the basis of microelectrode behavior of the silver nuclei and wire. AFM, SEM, light microscopy and single crystal X-ray diffraction has been applied to study the morphology of the silver nuclei and wires.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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