Visible-light sensitization of boron-doped nanocrystalline diamond through non-covalent surface modification

Literature Information

Publication Date 2014-11-05
DOI 10.1039/C4CP04148H
Impact Factor 3.676
Authors

Hana Krysova, Zuzana Vlckova-Zivcova, Jan Barton, Vaclav Petrak, Milos Nesladek, Petr Cigler, Ladislav Kavan


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Abstract

A novel simple and versatile synthetic strategy is developed for the surface modification of boron-doped diamond. In a two-step procedure, polyethyleneimine is adsorbed on the hydrogenated diamond surface and subsequently modified with a model light-harvesting donor-π-bridge-acceptor molecule (coded P1). The sensitized diamond exhibits stable cathodic photocurrents under visible-light illumination in aqueous electrolyte solution with dimethylviologen serving as an electron mediator. In spite of the simplicity of the surface sensitization protocol, the photoelectrochemical performance is similar to or better than that of other sensitized diamond electrodes which were reported in previous studies (2008–2014).

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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