Double-quantum 19F–19F dipolar recoupling at ultra-fast magic angle spinningNMR: application to the assignment of 19F NMR spectra of inorganic fluorides

Literature Information

Publication Date 2009-09-23
DOI 10.1039/B914468D
Impact Factor 3.676
Authors

Bingwen Hu, Franck Fayon, Julien Trébosc, Christophe Legein, Olivier Lafon, Feng Deng, Jean-Paul Amoureux


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Abstract

A broadband dipolar recoupling method robust to chemical shift is introduced to observe 19F–19F proximities in fluoroaluminates in high magnetic field and at ultra-fast magic angle spinning (>60 kHz).

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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