Selective removal of acetylenes from olefin mixtures through specific physicochemical interactions of ionic liquids with acetylenes

Literature Information

Publication Date 2009-11-07
DOI 10.1039/B915989D
Impact Factor 3.676
Authors

Jung Min Lee, Jelliarko Palgunadi, Jin Hyung Kim, Srun Jung, Young-seop Choi, Minserk Cheong, Hoon Sik Kim


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Abstract

Imidazolium-based ionic liquids (ILs) bearing an alkylphosphite anion, were highly efficient for the selective removal of acetylenes in olefins. Comparison of solubility data at 313 K and at atmospheric pressure shows that the solubilities of acetylene and propyne in 1,3-dimethylimidazolium methylphosphite ([DMIM][MeHPO3]) are about 45 and 20 times higher than those of ethylene and propylene, respectively. Computational and 1H NMR results clearly demonstrate that there are substantial interactions between the acidic hydrogen atom or atoms of acetylenes and the phosphite anion.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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