Cooperative structure-directing effect in the synthesis of aluminophosphate molecular sieves in ionic liquids
Literature Information
Renshun Xu, Xiaochao Shi, Weiping Zhang, Yunpeng Xu, Zhijian Tian, Xiaobing Lu, Xiuwen Han, Xinhe Bao
In situ two-dimensional NMR and fluorescence emission spectroscopy were employed to investigate the cooperative structure-direction effect of organic amine such as morpholine in the synthesis of aluminophosphate molecular sieves in ionic liquids. In situ rotating frame nuclear Overhauser effect spectra (ROESY) together with fluorescence measurements demonstrate that the aggregates between imidazolium cations and morpholines through intermolecular hydrogen bonds can be formed in the gel during the crystallization of molecular sieves. Combining with the characterizations of the solid products by solid-state NMR, it is verified that different aggregates of organic amines with imidazolium cations, which is similar to self-assembled supramolecular analogues, could act as the structure-directing agents for selective tuning of the framework topologies such as AEL, AFI and LTA in the final solid products.
Recommended Journals

Main Group Metal Chemistry

Current Medicinal Chemistry

Advanced Composite Materials

Chemistry of Materials

Computational Materials Science

Cement and Concrete Composites

Applied Composite Materials

Journal of Physical Organic Chemistry

Construction and Building Materials

Journal of Computer-Aided Molecular Design
Related Literature
Rotationally resolved electronic spectroscopy of 3-cyanoindole and the 3-cyanoindole–water complex
Michael Schneider, Marie-Luise Hebestreit, Mirko Matthias Lindic, Hilda Parsian, América Yareth Torres-Boy, Leonardo Álvarez-Valtierra, W. Leo Meerts, Ralf Kühnemuth, Michael Schmitt
DOI: 10.1039/C8CP04020F
Short-range ion dynamics in methylammonium lead iodide by multinuclear solid state NMR and 127I NQR
Alessandro Senocrate, Igor Moudrakovski, Joachim Maier
DOI: 10.1039/C8CP01535J
Anomalous fluorescence enhancement and fluorescence quenching of graphene quantum dots by single walled carbon nanotubes
Ruma Das, Gone Rajender
DOI: 10.1039/C7CP06994D
Harvesting visible light with MoO3 nanorods modified by Fe(iii) nanoclusters for effective photocatalytic degradation of organic pollutants
U. Alam, S. Kumar, J. Koch, C. Tegenkamp, M. Muneer
DOI: 10.1039/C7CP08206A
Thermodynamic and kinetic isotope effects on the order–disorder transition of ice XIV to ice XII
Violeta Fuentes-Landete, Karsten W. Köster, Roland Böhmer, Thomas Loerting
DOI: 10.1039/C8CP03786H
Unraveling doping induced anatase–rutile phase transition in TiO2 using electron, X-ray and gamma-ray as spectroscopic probes
D. Banerjee, Santosh K. Gupta, N. Patra, Sk Wasim Raja, N. Pathak, D. Bhattacharyya, P. K. Pujari, S. V. Thakare, S. N. Jha
DOI: 10.1039/C8CP04310H
Crystallization kinetics of water on graphite
Takashi Aizawa
DOI: 10.1039/C8CP03000F
A hybrid hydrazine redox flow battery with a reversible electron acceptor
Swapnil Varhade, Zahid M. Bhat, Ravikumar Thimmappa, Mruthyunjayachari C. Devendrachari, Alagar R. Kottaichamy, Manu Gautam, Shahid P. Shafi, Musthafa Ottakam Thotiyl
DOI: 10.1039/C8CP03768J
Unravelling the mechanisms of interference between overlapping resonances
DOI: 10.1039/C7CP07769F
Group-VIII transition metal boride as promising hydrogen evolution reaction catalysts
Guang-Feng Wei, Ling-Ran Zhang, Zhi-Pan Liu
DOI: 10.1039/C8CP05079A
You might also like
Is 6-(3-Fluorophenyl)picolinic acid (CAS: 887982-40-3) safe?
6-(3-Fluorophenyl)picolinic acid is generally considered safe for laboratory use...
What industries use (3R)-3-Pyrrolidinol (CAS: 2799-21-5)?
(3R)-3-Pyrrolidinol is used in the pharmaceutical industry as a precursor for dr...
What precautions should be taken when handling (4R,5R)-4,5-Diethoxycarbonyl-2,2-dimethyldioxolane (CAS: 59779-75-8)?
When handling (4R,5R)-4,5-Diethoxycarbonyl-2,2-dimethyldioxolane (CAS: 59779-75-...
How is 1-(6-Chloroimidazo[1,2-b]pyridazin-3-yl)ethanone (CAS: 90734-71-7) typically synthesized?
1-(6-Chloroimidazo[1,2-b]pyridazin-3-yl)ethanone is often synthesized via a mult...
What is the market or research trend for N-Ethyl-3,4-dimethylbenzylamine (CAS: 39180-83-1)?
The market for N-Ethyl-3,4-dimethylbenzylamine (CAS: 39180-83-1) remains steady,...
What is Tert-butyl 3-(pyrrolidin-1-yl)azetidine-1-carboxylate (CAS: 1019008-21-9)?
Tert-butyl 3-(pyrrolidin-1-yl)azetidine-1-carboxylate is a chemical compound wit...
What regulatory guidelines apply to 1-Bromo-3-chloro-2,4-dimethoxybenzene (CAS: 1228956-93-1)?
1-Bromo-3-chloro-2,4-dimethoxybenzene (CAS: 1228956-93-1) falls under the classi...
Is 8-Bromo-2-methyl-3,4-dihydroisoquinolin-1(2H)-one (CAS: 1368622-07-4) safe?
The safety of 8-Bromo-2-methyl-3,4-dihydroisoquinolin-1(2H)-one (CAS: 1368622-07...
Is Benzyl [(3S)-2,6-dioxo-3-piperidinyl]carbamate (CAS: 22785-43-9) safe?
Benzyl [(3S)-2,6-dioxo-3-piperidinyl]carbamate is generally safe when handled wi...
How should 1-{[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]sulfonyl}pyrrolidine (CAS: 928657-21-0) be stored?
1-{[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]sulfonyl}pyrrolidine s...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.




