Metal–organic frameworks as high-potential adsorbents for liquid-phase separations of olefins, alkylnaphthalenes and dichlorobenzenes

Literature Information

Publication Date 2009-03-05
DOI 10.1039/B823233D
Impact Factor 3.676
Authors

Luc Alaerts, Michael Maes, Monique A. van der Veen, Pierre A. Jacobs, Dirk E. De Vos


View Original

Abstract

Three metal–organic frameworks (MOFs) with similar pore window diameters, [Cu3(BTC)2], MIL-47 and MIL-53(Al), are tested for adsorption of olefins, alkylnaphthalenes and dichlorobenzenes in the liquid phase. Selective adsorption of olefins is possible only on [Cu3(BTC)2] viaπ-complexation on its open metal sites. This material shows a remarkable preference for cis-olefins over trans-olefins. All three MOFs have high affinities for alkylnaphthalene and dichlorobenzene isomers. Separation of 1,4-dimethylnaphthalene from other alkylnaphthalene isomers and of p- and m-dichlorobenzene can be carried out on both MIL-47 and MIL-53(Al), as shown with breakthrough experiments. For the alkylnaphthalenes, column experiments at different concentrations point to enthalpic interactions as important factors determining selectivity, and the occurrence of steric effects during the adsorption of 1,4-dimethylnaphthalene shows that its kinetic diameter approaches the pore diameter of the adsorbents. For the dichlorobenzenes, packing effects dominate the adsorption selectivity.

Related Literature

Tl2S: a metal-shrouded two-dimensional semiconductor

Shiying Shen, Yan Liang, Yandong Ma, Baibiao Huang, Wei Wei, Ying Dai

2018-05-09 Paper

DOI: 10.1039/C8CP02303D

Probing the interaction between solid benzene and water using vacuum ultraviolet and infrared spectroscopy

Anita Dawes, Natalia Pascual, Nigel J. Mason, Sabrina Gärtner, Søren V. Hoffmann, Nykola C. Jones

2018-05-11 Paper

DOI: 10.1039/C8CP01228H

Front cover

Cover

DOI: 10.1039/C8CP90032A

The ortho-benzyne cation is not planar

D. Kaiser, E. Reusch, P. Hemberger, A. Bodi, E. Welz, B. Engels, I. Fischer

2018-01-09 Paper

DOI: 10.1039/C7CP08055G

Polydopamine and eumelanin models in various oxidation states

Chun-Teh Chen, Markus J. Buehler

2018-10-09 Paper

DOI: 10.1039/C8CP05037F

‘Nano on micro’ hierarchical porous all carbon structures: an insight into interfacial interactions with bacteria

Shriram Janghela, Nagendra Singh Neeraj, Kavita Agarwal, Debmalya Roy, Kingsuk Mukhopadhyay, Namburi Eswara Prasad

2018-11-06 Paper

DOI: 10.1039/C8CP05570J

Structure and dynamics of high-temperature strontium aluminosilicate melts

Pierre Florian, James W. E. Drewitt, Louis Hennet, Vincent Sarou-Kanian, Dominique Massiot, Henry E. Fischer, Daniel R. Neuville

2018-10-12 Paper

DOI: 10.1039/C8CP04908D

Thermodynamic and kinetic isotope effects on the order–disorder transition of ice XIV to ice XII

Violeta Fuentes-Landete, Karsten W. Köster, Roland Böhmer, Thomas Loerting

2018-08-13 Paper

DOI: 10.1039/C8CP03786H

Linear humidity response of carbon dot-modified molybdenum disulfide

Guili He, Da Huang, Zhi Yang, Yutong Han, Jun Hu, Nantao Hu, Yanjie Su, Zhihua Zhou, Yafei Zhang, Yan Zhang

2018-01-04 Paper

DOI: 10.1039/C7CP07125F

High-resolution broadband sum frequency generation vibrational spectroscopy using intrapulse interference

Yang Wang, Xiangyun Ma, Huijie Wang, Da Chen, Keng C. Chou, Qifeng Li

2018-07-31 Communication

DOI: 10.1039/C8CP02519C

You might also like

Compound Q&A

Is 6-(3-Fluorophenyl)picolinic acid (CAS: 887982-40-3) safe?

6-(3-Fluorophenyl)picolinic acid is generally considered safe for laboratory use...

887982-40-36-(3-Fluorophenyl)pi...
Compound Q&A

What industries use (3R)-3-Pyrrolidinol (CAS: 2799-21-5)?

(3R)-3-Pyrrolidinol is used in the pharmaceutical industry as a precursor for dr...

2799-21-5(3R)-3-Pyrrolidinol
Compound Q&A

What precautions should be taken when handling (4R,5R)-4,5-Diethoxycarbonyl-2,2-dimethyldioxolane (CAS: 59779-75-8)?

When handling (4R,5R)-4,5-Diethoxycarbonyl-2,2-dimethyldioxolane (CAS: 59779-75-...

59779-75-8(4R,5R)-4,5-Diethoxy...
Compound Q&A

How is 1-(6-Chloroimidazo[1,2-b]pyridazin-3-yl)ethanone (CAS: 90734-71-7) typically synthesized?

1-(6-Chloroimidazo[1,2-b]pyridazin-3-yl)ethanone is often synthesized via a mult...

90734-71-71-(6-Chloroimidazo[1...
Compound Q&A

What is the market or research trend for N-Ethyl-3,4-dimethylbenzylamine (CAS: 39180-83-1)?

The market for N-Ethyl-3,4-dimethylbenzylamine (CAS: 39180-83-1) remains steady,...

39180-83-1N-Ethyl-3,4-dimethyl...
Compound Q&A

What is Tert-butyl 3-(pyrrolidin-1-yl)azetidine-1-carboxylate (CAS: 1019008-21-9)?

Tert-butyl 3-(pyrrolidin-1-yl)azetidine-1-carboxylate is a chemical compound wit...

1019008-21-9Tert-butyl 3-(pyrrol...
Compound Q&A

What regulatory guidelines apply to 1-Bromo-3-chloro-2,4-dimethoxybenzene (CAS: 1228956-93-1)?

1-Bromo-3-chloro-2,4-dimethoxybenzene (CAS: 1228956-93-1) falls under the classi...

1228956-93-11-Bromo-3-chloro-2,4...
Compound Q&A

Is 8-Bromo-2-methyl-3,4-dihydroisoquinolin-1(2H)-one (CAS: 1368622-07-4) safe?

The safety of 8-Bromo-2-methyl-3,4-dihydroisoquinolin-1(2H)-one (CAS: 1368622-07...

1368622-07-48-Bromo-2-methyl-3,4...
Compound Q&A

Is Benzyl [(3S)-2,6-dioxo-3-piperidinyl]carbamate (CAS: 22785-43-9) safe?

Benzyl [(3S)-2,6-dioxo-3-piperidinyl]carbamate is generally safe when handled wi...

22785-43-9Benzyl [(3S)-2,6-dio...
Compound Q&A

How should 1-{[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]sulfonyl}pyrrolidine (CAS: 928657-21-0) be stored?

1-{[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]sulfonyl}pyrrolidine s...

928657-21-01-{[4-(4,4,5,5-Tetra...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.