Interactions between co-adsorbed CO and H on a Rh(100) single crystal surface
Literature Information
Maarten M. M. Jansen, Jose Gracia, Ben E. Nieuwenhuys, (Hans) J. W. Niemantsverdriet
Co-adsorption of CO and H2 on a Rh(100) single crystal surface has been studied by a combination of temperature programmed desorption (TPD), reflection absorption infrared spectroscopy (RAIRS), low energy electron diffraction (LEED), and density functional theory (DFT) calculations. Exposure of CO to a hydrogen precovered surfaces at 150 K results in some displacement of adsorbed hydrogen and a layer with 0.67 ML H and 0.67 ML CO is obtained. A c(3√2 ×√2)R45° structure is formed with CO occupying bridge sites and hydrogen occupying partly bridge sites on the surface and partly octahedral subsurface sites, causing hydrogen to desorb at temperatures around 230 K.
Recommended Journals
Related Literature
J-aggregation of ionic liquid solutions of meso-tetrakis(4-sulfonatophenyl)porphyrin
Maroof Ali, Vinod Kumar, Sheila N. Baker, Gary A. Baker, Siddharth Pandey
DOI: 10.1039/B920500D
A liposome-based energy conversion system for accelerating the multi-enzyme reactions‡
Ryuhei Matsumoto, Masaya Kakuta, Taiki Sugiyama, Yoshio Goto, Hideki Sakai, Yuichi Tokita, Tsuyonobu Hatazawa, Seiya Tsujimura, Osamu Shirai, Kenji Kano
DOI: 10.1039/C0CP00556H
First observation in the gas phase of the ultrafast electronic relaxation pathways of the S2 states of heme and hemin
Minh-Huong Ha-Thi, Niloufar Shafizadeh, Lionel Poisson, Benoit Soep
DOI: 10.1039/C0CP00687D
A new battery-charging method suggested by molecular dynamics simulations
Ibrahim Abou Hamad, D. O. Wipf, P. A. Rikvold
DOI: 10.1039/B920970K
Accurate quantum chemical energies for the interaction of hydrocarbons with oxide surfaces: CH4/MgO(001)
Sergio Tosoni, Joachim Sauer
DOI: 10.1039/C0CP01261K
Boundary effects on the electrical conductivity of pure and doped cerium oxide thin films
Marcus C. Göbel, Giuliano Gregori, Joachim Maier
DOI: 10.1039/C0CP00385A
Quantum-chemical study and FTIR jet spectroscopy of CHCl3–NH3 association in the gas phase
Michael Hippler, Susanne Hesse, Martin A. Suhm
DOI: 10.1039/C0CP00530D
Ionic liquids through the looking glass: theory mirrors experiment and provides further insight into aromatic substitution processes
Shon Glyn Jones, Hon Man Yau, Erika Davies, James M. Hook, Tristan G. A. Youngs, Jason B. Harper, Anna K. Croft
DOI: 10.1039/B919831H
The influence of π–π-stacking on the light-harvesting properties of perylene bisimide antennas that are covalently linked to a [60]fullerene
Christiane C. Hofmann, Stefan M. Lindner, Michaela Ruppert, Andreas Hirsch, Saif A. Haque, Mukundan Thelakkat, Jürgen Köhler
DOI: 10.1039/C0CP01200A
New nearly constant loss feature detected in glass at low temperatures
David M. Laughman, Radha D. Banhatti, Klaus Funke
DOI: 10.1039/C0CP00765J
You might also like
Is 6-(3-Fluorophenyl)picolinic acid (CAS: 887982-40-3) safe?
6-(3-Fluorophenyl)picolinic acid is generally considered safe for laboratory use...
What industries use (3R)-3-Pyrrolidinol (CAS: 2799-21-5)?
(3R)-3-Pyrrolidinol is used in the pharmaceutical industry as a precursor for dr...
What precautions should be taken when handling (4R,5R)-4,5-Diethoxycarbonyl-2,2-dimethyldioxolane (CAS: 59779-75-8)?
When handling (4R,5R)-4,5-Diethoxycarbonyl-2,2-dimethyldioxolane (CAS: 59779-75-...
How is 1-(6-Chloroimidazo[1,2-b]pyridazin-3-yl)ethanone (CAS: 90734-71-7) typically synthesized?
1-(6-Chloroimidazo[1,2-b]pyridazin-3-yl)ethanone is often synthesized via a mult...
What is the market or research trend for N-Ethyl-3,4-dimethylbenzylamine (CAS: 39180-83-1)?
The market for N-Ethyl-3,4-dimethylbenzylamine (CAS: 39180-83-1) remains steady,...
What is Tert-butyl 3-(pyrrolidin-1-yl)azetidine-1-carboxylate (CAS: 1019008-21-9)?
Tert-butyl 3-(pyrrolidin-1-yl)azetidine-1-carboxylate is a chemical compound wit...
What regulatory guidelines apply to 1-Bromo-3-chloro-2,4-dimethoxybenzene (CAS: 1228956-93-1)?
1-Bromo-3-chloro-2,4-dimethoxybenzene (CAS: 1228956-93-1) falls under the classi...
Is 8-Bromo-2-methyl-3,4-dihydroisoquinolin-1(2H)-one (CAS: 1368622-07-4) safe?
The safety of 8-Bromo-2-methyl-3,4-dihydroisoquinolin-1(2H)-one (CAS: 1368622-07...
Is Benzyl [(3S)-2,6-dioxo-3-piperidinyl]carbamate (CAS: 22785-43-9) safe?
Benzyl [(3S)-2,6-dioxo-3-piperidinyl]carbamate is generally safe when handled wi...
How should 1-{[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]sulfonyl}pyrrolidine (CAS: 928657-21-0) be stored?
1-{[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]sulfonyl}pyrrolidine s...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.













![Benzyl spiro[indole-3,4'-piperidine]-1(2H)-carboxylate hydrochloride (1:1) structure Benzyl spiro[indole-3,4'-piperidine]-1(2H)-carboxylate hydrochloride (1:1) structure](https://static.chemtradehub.com/structs/159/159635-46-8-8de0.webp)