The influence of π–π-stacking on the light-harvesting properties of perylene bisimide antennas that are covalently linked to a [60]fullerene

Literature Information

Publication Date 2010-10-07
DOI 10.1039/C0CP01200A
Impact Factor 3.676
Authors

Christiane C. Hofmann, Stefan M. Lindner, Michaela Ruppert, Andreas Hirsch, Saif A. Haque, Mukundan Thelakkat, Jürgen Köhler


View Original

Abstract

A flexible organic triad consisting of two perylene bisimide antennas covalently linked to a [60]fullerene by flexible spacers has been synthesized and studied by electrochemistry, steady-state and time-resolved spectroscopy. We found that π–π-stacking of the two antenna subunits has considerable impact on the photophysics of the system and leads to a reduction of the effective light-harvesting efficiency of the assembly. This finding is important for light harvesting in flexible materials based on the dye antenna–fullerene concept.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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