Room temperature benzene C–H activation by a new [PSiP]Ir pincer complex
Literature Information
Darren F. MacLean, Robert McDonald, Michael J. Ferguson, Andrew J. Caddell, Laura Turculet
The synthesis and reactivity of coordinatively unsaturated Rh and Ir complexes supported by the new bis(phosphino)silyl pincer ligand [κ3-(2-Cy2PC6H4)2SiMe]− ([Cy-PSiP]−) are reported, including the first example of facile, room temperature intermolecular arene C–H bond activation mediated by a silyl pincer complex.
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