Electron-rich heteroaromatic conjugated bipyridine based ruthenium sensitizer for efficient dye-sensitized solar cells
Literature Information
Alessandro Abbotto, Claudia Barolo, Luca Bellotto, Filippo De Angelis, Michael Grätzel, Norberto Manfredi, Chiara Marinzi, Simona Fantacci, Jun-Ho Yum, Mohammad K. Nazeeruddin
A novel heteroleptic ruthenium complex carrying a heteroaromatic-4,4′-π-conjugated 2,2′-bipyridine [Ru(II)LL′(NCS)2] (L = 4,4′-bis[(E)-2-(3,4-ethylenedioxythien-2-yl)vinyl]-2,2′-bipyridine, L′ = 4,4′-(dicarboxylic acid)-2,2′-bipyridine) was synthesized and used in dye-sensitized solar cells, yielding photovoltaic efficiencies of 9.1% under standard global AM 1.5 sunlight.
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