Relative importance of hydrogen bonding and coordinating groups in modulating the zinc–water acidity

Literature Information

Publication Date 2003-11-04
DOI 10.1039/B310956A
Impact Factor 6.222
Authors

Juan C. Mareque-Rivas, Ravi Prabaharan, Rafael Torres Martín de Rosales


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Abstract

The presence of second-sphere –NH2 groups in the proximity of a zinc(II)-bound water molecule enhances its acidity by ca. 2 pKa units.

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