Use and recovery of a homogeneous catalyst with carbon dioxide as a solubility switch

Literature Information

Publication Date 2003-11-03
DOI 10.1039/B311146F
Impact Factor 6.222
Authors

Christopher D. Ablan, Jason P. Hallett, Kevin N. West, Rebecca S. Jones, Charles A. Eckert, Charles L. Liotta, Philip G. Jessop


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Abstract

A method for fluorous biphasic catalysis is described, in which the fluorous liquid is replaced by fluorinated silica, the fluorous catalyst is induced to dissolve in the organic solvent by the presence of CO2, and the recovery of the catalyst after the reaction is achieved by release of the CO2 pressure.

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