Selective 1,3-complexation of p-tBu-calix[4]arene by [TiCp2Me2]

Literature Information

Publication Date 2003-11-25
DOI 10.1039/B309455C
Impact Factor 6.222
Authors

Colin L. Raston


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Abstract

Reaction of p-tBu-calix[4]arene with dimethyl titanocene results in high yield selective 1,3-dimetallation of the calixarene in the cone conformation by selective cleavage of one methyl group.

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