Efficient symmetry-based homonuclear dipolar recoupling of quadrupolar spins: double-quantum NMR correlations in amorphous solids
Literature Information
Andy Y. H. Lo, Mattias Edén
We report novel symmetry-based pulse sequences for exciting double-quantum (2Q) coherences between the central transitions of half-integer spin quadrupolar nuclei in the NMR of rotating solids. Compared to previous 2Q-recoupling techniques, numerical simulations and 23Na and 27Al NMR experiments on Na2SO4 and the open-framework aluminophosphate AlPO-CJ19 verify that the new dipolar recoupling schemes display higher robustness to both radio-frequency field inhomogeneity and to spreads in resonance frequencies. These advances allowed for the first demonstration of 2Q-recoupling in an amorphous solid for revealing its intermediate-range structural features, in the context of mapping 27Al–27Al connectivities between the aluminium polyhedra (AlO4, AlO5 and AlO6) of a lanthanum aluminate glass (La0.18Al0.82O1.5).
Recommended Journals
Related Literature
Influence of Mn co-doping on the magnetic properties of planar arrays of GaxFe4−xN nanocrystals in a GaN matrix
L. Del Bianco, F. Spizzo, Tian Li, R. Adhikari, A. Bonanni
DOI: 10.1039/C8CP04475A
Swelling behaviour of core–shell microgels in H2O, analysed by temperature-dependent FTIR spectroscopy
Lars Wiehemeier, Oliver Wrede, Julian Oberdisse, Thomas Hellweg, Tilman Kottke
DOI: 10.1039/C8CP05911J
In situ XPS analysis of the atomic layer deposition of aluminium oxide on titanium dioxide
Robert H. Temperton, Andrew Gibson, James N. O'Shea
DOI: 10.1039/C8CP06912C
Structure, orientation, and dynamics of water-soluble ions adsorbed to basal surfaces of calcium monosulfoaluminate hydrates
Shahin Hajilar
DOI: 10.1039/C8CP03872D
Base adsorption mechanism over zeolite catalysts at different Al contents probed by the tapered element oscillating microbalance (TEOM)
Pierre Bräuer, Carmine D’Agostino
DOI: 10.1039/C8CP05001E
Metalation and coordination reactions of 2H-meso-trans-di(p-cyanophenyl)porphyrin on Ag(111) with coadsorbed cobalt atoms
DOI: 10.1039/C8CP05255G
Polyamidoxime chain length drives emergent metal-binding phenomena‡
L. D. Earl, C. Do, Y. Wang, C. W. Abney
DOI: 10.1039/C8CP02198H
Charge-patching method for the calculation of electronic structure of polypeptides
Fu Ding, Lin-Wang Wang
DOI: 10.1039/C8CP01803K
Charge transport parameters for carbon based nanohoops and donor–acceptor derivatives
Ángel José Pérez-Jiménez, Juan-Carlos Sancho-García
DOI: 10.1039/C8CP06727A
Doping effect on the local structure of metamagnetic Co doped Ni/NiO:GO core–shell nanoparticles using X-ray absorption spectroscopy and the pair distribution function
U. P. Gawai, D. K. Gaikwad, M. R. Bodke, H. A. Khawal, K. K. Pandey, A. K. Yadav, S. N. Jha, D. Bhattacharyya, B. N. Dole
DOI: 10.1039/C8CP05267K
You might also like
How is 3-(2-Bromoimidazo[2,1-b]thiazol-6-yl)propanoic acid hydrochloride (CAS: 1187830-80-3) typically synthesized?
3-(2-Bromoimidazo[2,1-b]thiazol-6-yl)propanoic acid hydrochloride is typically s...
How is 2-Isopropyl-1,3-dioxane-5-carboxylic acid (CAS: 116193-72-7) typically synthesized?
2-Isopropyl-1,3-dioxane-5-carboxylic acid is typically synthesized by the carbox...
What is Alisporivir (CAS: 254435-95-5)?
Alisporivir (CAS: 254435-95-5) is an antiviral medication used in the treatment ...
What are the physical and chemical properties of [1,2,4]triazolo[3,4-a]phthalazine (CAS: 234-80-0)?
[1,2,4]triazolo[3,4-a]phthalazine (CAS: 234-80-0) is a crystalline compound with...
What regulatory guidelines apply to (2S)-5-Hydroxy-2-(4-hydroxyphenyl)-4-oxo-3,4-dihydro-2H-chromen-7-yl methyl beta-D-glucopyranosiduronate (CAS: 1985597-72-5)?
Regulatory guidelines for (2S)-5-Hydroxy-2-(4-hydroxyphenyl)-4-oxo-3,4-dihydro-2...
Is 2,2-Difluorocyclohexanamine hydrochloride (CAS: 921602-83-7) safe?
2,2-Difluorocyclohexanamine hydrochloride is generally safe when handled under p...
What are the main uses of 3-Nitro-2-phenylthiophene (CAS: 18150-94-2)?
3-Nitro-2-phenylthiophene is primarily used in the synthesis of other organic co...
What is 1-(Trifluoroacetyl)-4-piperidinecarbonitrile (CAS: 77940-79-5)?
1-(Trifluoroacetyl)-4-piperidinecarbonitrile (CAS: 77940-79-5) is a colorless to...
What is the market or research trend for 1,3,6,8-Tetranitro-9H-carbazole (CAS: 4543-33-3)?
Research and market trends for 1,3,6,8-Tetranitro-9H-carbazole (CAS: 4543-33-3) ...
How should waste containing Dibenzo[b,d]thiophen-1-ylboronic acid (CAS: 1245943-60-5) be handled?
Waste containing Dibenzo[b,d]thiophen-1-ylboronic acid (CAS: 1245943-60-5) shoul...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.











![[3-Fluoro-5-(2,2,2-trifluoroethoxy)phenyl]boronic acid structure [3-Fluoro-5-(2,2,2-trifluoroethoxy)phenyl]boronic acid structure](https://static.chemtradehub.com/structs/850/850589-55-8-a8ed.webp)
![Potassium trifluoro[(2-methoxyethoxy)methyl]borate(1-) structure Potassium trifluoro[(2-methoxyethoxy)methyl]borate(1-) structure](https://static.chemtradehub.com/structs/910/910251-13-7-2d3a.webp)

