Atom efficient cyclotrimerization of dimethylcyanamide catalyzed by aluminium amide: a combined experimental and theoretical investigation

Literature Information

Publication Date 2008-06-20
DOI 10.1039/B803732A
Impact Factor 6.222
Authors

Peter Dornan, Christopher N. Rowley, Jessica Priem, Seán T. Barry, Tara J. Burchell, Tom K. Woo, Darrin S. Richeson


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Abstract

A novel method for the cyclotrimerization of dimethylcyanamide to form hexamethylmelamine has been developed using an aluminium amide catalyst; detailed DFT modelling of the catalytic cycle supports a triple insertion, nucleophilic ring closure, deinsertion mechanism.

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